合成气制乙二醇装置迈向大型化.pdfVIP

96 石 油 炼 制 与 化 工 2014年 第 45卷 [3] ASTM Internationa1．E1269StandardTestMethodforDe一 [6] AtkinsonCM ，LarkinJA，RichardsonM J．Thermalproper term ining Specific HeatCapacity by DifferentialScanning tiesofstirrercrystallizedpolyethylene[J]．Polymer，1969， Calorimetry[S]．2005 10：127一l34 [4] ASTM Internationa1．D2766StandardTestMethodforSpe [7] FrancisPG．A flow calorimeterforthemeasurementofthe cificHeatofLiquidsandSolids[S]．2005 heatcapacitiesandjoulethomsoncoefficients[J]．Journalof [5] 梁文杰．石油化学[M]．东营 ：石油大学出版社，1995：116-117 ChemicalThermodynamics，1990，22(6)：545—556 FACToRSAFFECTING HEAT CAPACITY OF TRANSFoRM ER OIL WangHuijuan ，YuHuimin ，MaShujie 。ZhangQi， (1．PetroChinaLanzhouLubricantRD Institute，Karamay，Xinjiang834003； 2．CNPCKeyLaboratoryofLubricatingOil) Abstract：In thiswork，severalliquid specificheatcapacitymeasuringmethodswereintroduced． Theeffectoftemperature，viscosity，refining depth andhydrocarbon composition on thespecificheat capacityoftransformeroi1wereinvestigatedusingthemeasuringmethods．Itisfoundthattherepeat— abilityofflow calorimetricmethod(ASTM D2766— 1995)withthedeviation lessthan ±2 ，isbetter than thatofthedifferentialscanning calorimetry (ASTM E1269-- 2005)method．The investigation findsthatthespecificheatcapacityoftransformeroilincreaseslinearlywith increasing temperaturein therangeof～ 20— 1OO℃ ．Theheatcapacityoftheoilsbytraditionalsolventrefiningishardlyaffected byrefiningdepthandadditives．Thetestresultsshow thatfortheoilswith thesameviscositybutdif— ferentaromaticcontents，theheatcapacitiesarebasicallythesameand thattheheatcapacitiesaredi rectlyrelatedtoalkanecontentbutincreasesslowlywithtemperatureforthehigheralkanecontentoils． Asaresult，theheatcapacitiesoftheoilswith differentalkanecontentareverycloseat100 ℃ ．W hile