催化剂对镁基储氢材料储氢性能影响的研究进展.。pdf.pdfVIP

催化剂对镁 储氢材料储氢性能影响的研究进展/ 蔡 浩等 ∀ 115 ∀ * 蔡 浩, 顾 昊, 朱云峰, 李李泉 ( , 210009) 综述了近年来添加过渡族金属金属氧化物和金属卤化物催化剂对镁 储氢材料性能影响的研究进 展, 总结了催化剂催化效果的影响因素比较发现, 多价态过渡族金属卤化物对镁 储氢材料具有最好的催化作用 催化剂作用机理包括: 为氢的扩散提供通道; 为氢的吸附离解提供活性位置; 起到 氢泵 的作用; 与 M gH 键发生电 子交互作用 Research Progress in the Influence of Catalysts on Hydrogen Storage Property of Magnesiumbased Hydrogen Storage Materials CAI Hao, GU Hao, ZHU Yunfeng, LI Liquan ( Colleg e of M ate ials Science and Eng inee ing, N anj ing U niv e sity of T echnolo gy , N anjing 210009) Abstract Resea ch p o g ess in the influence of the catalysts of t ansition meta l, metal ox ides and metal halides on the hy d og en sto age pe fo mance of M gbased hy d og en sto ag e mat e ials is eviewed in this pape . Influence fac to s of catalyt ic effect of cat alysts a e summa ized. By compa ison, multivalent t ansition metal halides have t he best cat alyt ic act ivity to the M gbased hy d og en sto age mat e ials. M echanism of catalysts includes: offe ing pathway fo hyd og en diffusion, supplying active sit e fo hy d og en adso ptio n and deco mpo sition, acting as hyd o gen pump and elect o nic int e actio n w ith M gH bonds. Key words M gbased hyd og en sto ag e mate ia ls, t ansition metal, metal o x ides, met al halides, catalysts , 0 M g H , 30~ 200! 2 , T i , VF eM n Ni , , V , T iF e N i M n 250~ 300! , M gH T i