TS_1钛硅分子筛制备研究新进展.pdf

25 现代化工 July 2005 2005 7 Modern Chemic l Industry # 23 # TS- 1 顾晓利, 乔 旭, 崔咪芬, 张进平, 汤吉海 ( 南京工业大学化学化工学院, 江苏 南京210009) : 2 : - , 2 , - , : ; ; ; ; :TQ426 :A : 0253- 4320( 2005) S1- 0023- 05 Advances in preparation technique for TS- 1 molecular sieve G UX iao-li, QIA O X u, CUI M i-f en, ZHANG Jin-p ing , TANG Ji-hai ( College of Chemistry nd Chemic l Engineering, N njing University of Technology, N njing 210009, Chin ) Abstract: TS- 1 molecul r sieve w s widely pplied in the green org nic oxid tion process with low concentr tion (30wt% ) of H O s oxid nt, which w s known s the typic l environment l friendly c t lytic re ction. In this p per, two 2 2 prep r tion methods for TS- 1 were reviewed in det ils, n mely the typic l hydrotherm l synthesis nd novel g s-solid isomorphous repl cement. Me nwhile, the problems bout TS- 1 pplic tion in industric l m nuf cture were lso pointed out. It w s concluded th t the g s-solid isomorphous repl cement is believed to be of more industri l prospect bec use of its low cost nd simple process. Key words: tit nium; silicon; molecul r sieve; c t lyst; prep r tion [ 1] 1983 TS- 1 TS- 1 (H O 30% ) , 2 2 , Ti- ZSM- 5, 2 [3] , TS- 1 Schultz TS- 1 X - , , - Ti- ZSM- 5 ,