钛铁矿(FeTiO3)粉末氧化过程中物相转变、微观形貌及其氧化机制.pdfVIP

Trans. Nonferrous Met. Soc. China 23(2013) 2439−2445 Phase transitions, micro-morphology and its oxidation mechanism in oxidation of ilmenite (FeTiO3) powder Wei XIAO, Xiong-gang LU, Xing-li ZOU, Xue-mei WEI, Wei-zhong DING Shanghai Key Laboratory of Modern Metallurgy and Materials Processing, Shanghai University, Shanghai 200072, China Received 21 June 2012; accepted 15 October 2012 Abstract: Phase transitions, morphology changes, and oxidation mechanism of the ilmenite oxidation process were investigated. FeTiO3 transforms to hematite and rutile when oxidation at 700−800 °C, and pseudobrookite is formed when the oxidation temperature reaches 900 °C. The initial ilmenite powder exhibits paramagnetism; however, after being oxidized at the intermediate temperature (800−850 °C), the oxidation product exhibits weak ferromagnetism. The oxidation mechanism was discussed. The microstructure observations show that a lot of micro-pores emerge on the surfaces of ilmenite particles at the intermediate temperature, which is deemed to be capable of enhancing the mass transfer of oxygen during oxidation. Key words: ilmenite; phase transitions; micro-morphology; oxidation mechanism the phase transition process during oxidation and the 1 Introduction phase composition in the oxidized products. At a lower temperature in the range of 500−800 °C, both r