聚丙烯腈基碳纤维高温石墨化综述_卢天豪.pdfVIP

38 3 Vol.38 No.3 2013 6 Hi-Tech Fiber Application Jun. 2013 1. 1000292. 100029 1 800 TQ342.743 A 1007-9815 2013 03-0046-08 High temperature graphitization of PAN-based carbon fi ber-a review 1 1 1,2 LU Tian-hao , LU Weng-qin , TONG Yuan-jian (1. College of Materials Science and Engineering, Beijing 100029 China; 2. Key Laboratory of Carbon Fiber and Functional Polymer, Ministry of Education, Beijing 100029 China) Abstract: With respect to key process of preparing polyacrynitrile-based high modulus carbon fibers, the basic graphitization process and the evolution of the composition, structures, tensile properties of carbon fiber during high temperature treatment were summarized and reviewed to provide a reference for developing and researching of carbon fibers with high strength and high modulus. It shows that one-step graphitization treatment process is good for keeping high strength of carbon fibers, and is a potential technology for industrial production. The lowest density of carbon fiber is found around treatment temperature of 1800oC. The modulus increases as a result of perfection of graphite crystal and decrease of interlayer spacing in the fibers. The method of catalytic graphitization, as well as treatment of high magnetic field, high energy electromagnetic radiatio