应用超临界CO 2制备微孔聚丙烯微孔形貌.pdfVIP

CO 2 许志美, 姜修磊, 刘 涛, 赵 玲, 朱中南 ( 华东理工大学化学工程联合国家重点实验室, 上 2002 37) : 研究了应用超临界CO2 技术制备微孔聚丙烯时发泡条件和聚丙烯( PP ) 的熔体 强度对微孔形貌的影响结果表明: 在一定的饱和压力下, 随着温度的升高, P P 的变形能力 改善, 有利于泡孔的长大随着饱和压力的增加, PP 的熔点降低, 升高压力和升高温度具有 一定的等同作用由于CO2 在P P 内分散的不同, 高压低温时得到的泡孔比高温低压时得 到的泡孔要规整降压速率对泡孔形貌的影响因饱和压力的大小而异, 饱和压力较高时随 着降压速率的提高, 孔密度增加, 泡孔形貌经历了一个从球体到多面体转变的过程由于 PP 熔体强度较低, 在发泡温度和PP 熔点之间非常接近时, CO2 气体容易冲破孔壁而使泡 孔呈开孔结构 : 聚丙烯 微孔聚合物 微孔形貌 超临界CO2 : T Q32 : A : 2007) Cell Morphology of Microcellular Polypropylene Prepared by Supercritical Carbon Dioxide X U Z himei, J IA N G Xiulei, L IU T ao, ZH A O Ling, ZH U Zhongnan ( St ate K ey L aborat ory o f Chemical Eng ineer ing, East China U niversity of Science and T echno log y, Sh angh ai 2002 37, China) Abstract: T he cell m orpho logy o f t he microcellular polypropylene ( P P) f oams pr ep ared by super crit ical car bo n diox ide w as st u died. A ccording t o t he result s, as t he f oaming t em perature increased at a given sat uration pressure, the cell size increased for an incr ease in t he defo rmabilit y of t he P P. T here is a so rt o f equ iv alence bet w een incr easing f oaming t em perat ure and incr easing saturat io n pres sure in t erm s of t he fo am abilit y . T he cell obtained at a higher sat uration pressur e w it h a lo w er fo am ing t em perat ure is m ore unif orm t h an th at obt ained at a lo w er pressure w it h a higher foaming temp erature because of the dif ferent dif f usivity of CO2 in P P. T he ef fect o f pressur e drop rat e o n cell m orpho logy varies w ith t he magnitu de of sat uration pressure. A t