F127对热致相分离法制备亲水性PVB_F127共混中空纤维膜性能影响_英文.pdfVIP

SEPARATION SCIENCE AND ENGINEERING Chinese Journal of Chemical Engineering, 18(2) 207—216 (2010) Effects of F127 on Properties of PVB/F127 Blend Hollow Fiber * Membrane via Thermally Induced Phase Separation 1,** 2 1 QIU Yunren (邱运仁) , Matsuyama Hideto (松山秀人) , ZHONG Hong (钟宏) , YE Hongqi (叶红齐)1 and HUANG Kelong (黄可龙)1 1 School of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China 2 Department of Chemical Science and Engineering, Kobe University, Rokkodai, Nada-ku, Kobe 657-8501, Japan Abstract Hydrophilic poly(vinyl butyral) (PVB)/Pluronic F 127 (F127) blend hollow fiber membranes were pre- pared via thermally induced phase separation (TIPS), and the effects of blend composition on the performance of hydrophilic PVB/F127 blend hollow fiber membrane were investigated. The addition of F127 to PVB/polyethylene glycol (PEG) system decreases the cloud point temperature, while the cloud point temperature increases slightly with the addition of F127 to 20% (by mass) PVB/F127/PEG200 system when the concentration of F127 is not higher than 5% (by mass). Light scattering results show that the initial inter-phase periodic distance formed from the phase separation of 20% (by mass) PVB/F127/PEG200 system decreases with the addition of F127, so does the growth rate during cooling process. The blend hollow fiber membrane prepared at air-gap 5mm, of which the water permeability increases and the rejection changes little with the increase of F127 concentration. For the membrane prepared at zero air-gap, both water permeability and