新型杂环化合物在1mol_LHCl中对Q235钢的缓蚀性能研究_闫莹.pdfVIP

19 6 腐蚀科学与防护技术 Vo.l 19 No. 6 2007 11 CORROSION SCIENCE AND PROTECTION TECHNOLOGY Nov. 2007 1mol/L HCl Q235 1, 2 1 3 1 闫莹 , 李伟华 , 邢少华 , 侯保荣 11 , 266071; 21 , 100039; 31 , 266071 : 5-[ ( 1H-1, 2, 4 - -1-) ] -1, 3, 4--2-( TAOT) 1 mol/L HC1 Q235(). , TAOT 1 mol/L HC1 Q235 891 1% , . TAOT , Langmu ir, , . : ; ; ; ; : TG174142 : A : 1002-6495( 2007) 06-0414-05 CORROSION INH IBITION OF M ILD STEEL BY NOVEL HETEROEROCYCLIC COMPOUND IN 1mol/L HCl SOLUTION 1, 2 1 3 1 YAN Y ing , LIW e-i hua , X ING Shao-hua , HOU Bao-rong 11Institute of Oceanology, Ch ineseA cademy of S ciences, Q ingdao 266071; 21Graduate School, ChineseA cademy of Sciences, Beij ing 100039, PR China; 31S ta teK ey aboratory ForM arine Corrosion and Protection, Qingdao 26607 1, PR Ch ina A stract: A new l s nthesized heteroerc clic compound, 5-( 1H-1, 2, 4-triazole-1-alk l)-1, 3, 4-oxad-i azole-2-th iol( TAOT), w as investigated as corrosion inhibitors for m ild steel in 1 mol/L HCl using w eigh t loss expermi ent, electrochem ical test and quantum chem ical calculations. Itw as turned out that the h ighest - 3 inh ib ition efficienc ofTAOT reached 8911% in 110 @ 10 mol/L HC l solution. The potentiod nam ic po- larization curves ofm ild steel in h drochloric acid contain ing these compounds show ed that both cathodic and anod ic processes of