_相变对多孔氮化硅陶瓷介电性能影响.pdfVIP

39 3 (Y La ) O · 475 · 1–x x 2 3 39 3 Vol. 39 No. 3 2 0 1 1 3 JOURNAL OF THE CHINESE CERAMIC SOCIETY March 2011 α/β 1 2 1 1 1 (1. 710048 2. 710072) 0.8 mm 55%α/β β() 1 400 α/ββ α/βε′tan δtan δ TQ174.1 A 0454–5648(2011)03–0475–06 Effect of α/β Phase Transformation on Dielectric Properties of Porous Silicon Nitride Ceramics 1 2 1 1 1 XU Jie ZHOU Wancheng WANG Junbo SU Xiaolei HE Xinhai (1. School of Mechanical and Electronics Engineering, Xi’an Polytechnic University, Xi’an 710048; 2. State Key Laboratory of Solidification Processing, Northwestern Polytechnical University, Xi’an 710072, China) Abstract: Low-density porous silicon nitride ceramics, which contained 0.8 mm spherical pores in diameter and had porosity of about 55%, were prepared through adding stearic acid by reactive sintering. The influence of α/β phase transformation on the dielectric properties of porous silicon nitride ceramics was investigated. Pleomorphic silicon nitride ceramics with different relative content (in mass, the same below) of β phase were obtained by setting the nitriding temperature and time. The results show that the α/β trans- formation occurs when the nitriding temperature is higher than 1 400 . The relative content of the β phase increases and the mor- phologies changes from an equiaxed shape to prismatic one with the increase of nitriding temperature and time. The dielectric con- stant ε′ and the dielectric loss tan δ of the samples increase because of the α/β transformation, and the change of