β-双酮三苯基膦混配铜（I）配合物合成、晶体结构修改稿.docVIP

β-双酮铜（I）配合物的合成、晶体结构 及陈士昆ab 赵祥华吴杰颖田玉鹏* (a 安徽大学化学与化工学院 合肥 230039) 摘要 按文献法合成了9-丁基-3-（4，4，4-三氟-1，3-丁二酮基）咔唑以L和三苯基为配体与硝酸铜、铜粉反应制备铜I)配合物利用红外光谱和元素分析表征单晶X-射线衍射配合物晶体结构，属于单斜晶系，P21/c空间群。晶胞参数：a = 1.6428(5) , b = 1.0434(5) nm, c = 2.8001(5) nm，V=4.800(3) nm 3，Z=4，Dc=1.313 Mg/m3，R [I2σ(I)] R1 = 0.0501, wR2 = 0.0808，该物的，β- 酮配体 LI) 处于畸变四面体。研究I)配合物，配合物溶液强荧光。 9-丁基-3-4，4，4-三氟-1，3-丁二酮基咔唑；铜I)配合物; 晶体结构 Synthesis, Crystal Structure and Fluorescent Property of β-diketone and Triphenylphosphine Copper(I) Mixed-Ligand Complex Chen Shi-Kuna,b, Zhao Xiang-Huaa, Wu Jie-Yinga, Tian Yu-Penga* (aDepartment of Chemistry and Chemical Engineering, Anhui University, Hefei 230039) (bDepartment of Chemistry and Chemical Engineering HuaiNan normal university, Huainan 232001) Abstract A β-Diketone ligand L (3- (4, 4, 4 - trifluorobutane -1, 3 - diketone) - 9 - butylcarbazole) was synthesized according to literature method. The copper (I) complex with fluorescent activity was prepared by the reaction of copper nitrate, copper, triphenylphosphine and L, which was characterized by elemental analysis and IR spectra. Its crystal structure was determined by single crystal X-ray diffraction analysis. The crystal belongs to monoclinic, P21/c space group. Cell parameters: a = 1.6428 (5) nm, b = 1.0434 (5) nm, c = 2.8001 (5) nm. V = 4.800 (3) nm3, Z = 4, Dc = 1.313 Mg/m3, R [I 2σ (I)] R1 = 0.0501, wR2 = 0.0808. The Cu(I) ion in the distorted tetrahedral copper(I) complex is coordinated by two O atoms from the two β-diketone ligands, and two P atoms from triphenylphosphine, respectively. Fluorescent properties of the the copper(I) complex was studied, indicating that the complex bears strong fluorescent emission in dichloromethane solution. Keywords 3-(4,4,4-trifluorobutane -1,3-diketone)-9- butylcarbazole; copper(I) complex; crystal structure 功能配合物在光物理和光化学发光器件及太阳能光伏电池[1,2] 等领域的应用日益受到重视。在功能配合物种，β-双酮配合物表现出大的摩尔消光系数、高的荧光量子产率[3] 以及对环境的高度灵敏性，在分子探针、光敏剂[4] 以及电致发光材料[5] 等方面有着广泛应用。因此，设计、合成新β-双酮配体，制备功能配合物，是近年来化学家和材料学家研究的热点之一[