表面引发聚合反应的研究进展.pdfVIP

17 6 化 学 进 展 Vol. 17 No. 6 2005 11 PROGRESS IN CHEMISTRY Nov. , 2005 表面引发聚合反应研究进展* * * 倪 刚 杨 武 何晓燕 薄丽丽 吕维莲 ( 西北师范大学化学化工学院甘肃省高分子材料重点 验室兰州 730070) 表面引发聚合反应作为一种新的聚合反应可广泛应用于固体基底的表面修饰与改性结合分 子自组装技术, 几乎各种类型的聚合反应都有可能在固体基底表面进行本文对表面引发聚合反应的研究 进展进行了综述, 对反应类型 验方法研究动向以及在合成聚合物刷形成图案化聚合物薄膜等方面的应 用与发展前景作了介绍与讨论 表面引发聚合反应 自组装单分子层 图案化聚合物薄膜 聚合物刷 : O631. 5 : A : 1005-281X( 2005) 06- 1074-07 Advances in Surface Initiated Polymerization * * N i Gang Yang Wu H e X iaoyan Bo Lili L Weilian ( College of Chemistr and Chemical Engineering, Northwest Normal Universit , Gansu Ke Laborator of Pol mer Materials, Lanzhou 730070, China) Abstract The recent developments of surface initiated pol merization are reviewed. Surface modification of the pol mers is an important area both for application and basic research. As a new kind of controlled pol merization techniques, surface initiated pol merization can be used to modif the surfaces of the solid materials and tailor substrate properties. It opens a new wa for the modification of solid substrates for their potential applications in a variet of technological fields. The theoretical and the experimental approaches and the research prospects of the surface initiated pol merization are extensivel introduced in this paper. The applications of this technique including the patterned nanostructures of pol mer films and pol mer brushes are also discussed in detail. Key words surface initiated pol merization; self-assembled monola er; patterning pol mer films; pol mer brushes ,