铝合金表面原位自组装超疏水膜层制备及耐蚀性能.pdfVIP

物理化学学报(Wuli Huaxue Xuebao) December A cta Phys. Chim. Sin., 2009, 25(12) ：2581-2589 2581 [Article] 铝合金表面原位自组装超疏水膜层的制备及耐蚀性能 松梅* 周思卓 刘建华 ( 京航空航天大学材料科学与工程学院, 空天材料与服役教育部重点实验室, 北京 100191) 摘要： 采用阳极氧化法在铝合金表面原位构造粗糙结构, 经表面自组装硅氧烷后得到超疏水自清洁表面, 与水 滴的接触角最大可达157.5毅依2.0 , 接触角滞后小于3 . 通过傅立叶变换红外(FT鄄IR)光谱分析仪、场发射扫描电 子显微镜(FE鄄SEM) 、能谱仪(EDS)、原子 显微镜(AFM)和接触角测试对阳极氧化电流密度、硅氧烷溶液中水的 含量和自组装时间等参数进行了分析, 并得到制备超疏水自清洁表面的最优工艺参数. FE鄄SEM 及AFM 的测试 结果表明, 由自组装硅氧烷膜层的无序性形成的纳米结构和阳极氧化构造的微米级粗糙结构与硅氧烷膜层的低 表面能的协同作用构成了稳定的超疏水表面. 电化学测试(动电位极化)的结果表明, 原位自组装超疏水膜层极大 地提高了铝合金的耐蚀性. 关键词： 超疏水; 原位; 自组装; 硅氧烷; 耐蚀性 中图分类号： O647; O646 Fabrication and Anti Corrosion Property of In situ Self Assembled Super Hydrophobic Films on Aluminum Alloys LI Song鄄Mei* ZHOU Si鄄Zhuo LIU Jian鄄Hua (Key Laboratory of Aerospac e Materials and Perf ormance of the Ministry of Education, School of Materials Science and Engineering, Beihang University, Beiji ng 100191, P. R. China) Abstract ： In situ rough structures on an aluminum alloy were formed by anodic oxidation method. After siloxane self鄄assembly on the rough structures, super鄄hydrophobic and self鄄cleaning films were fabricated. The static contact angle of the super鄄hydrophobic surface with a water drop was 157.5毅依2.0 at its maximum and the contact angle hysteresis was less than 3 . The influence of anodic oxidation current density, the water content of the siloxane solution, and self鄄assembly time on film formation were studied by Fourier transform infrar