纳米二氧化钛膜催化剂制备及光催化活性研究.pdfVIP

纳米二氧化钛膜催化剂的制备及其光催化活性的研究 耿启金 郭庆杰* 青岛科技大学化工学院，山东省清洁化工过程重点实验室，山东，青岛， 266042 摘要 本文采用溶胶-凝胶法，利用钛酸丁酯为前驱体，在光催化反应器内壁上利用旋转涂膜法制备了纳 米二氧化钛膜催化剂，并利用热重-差热分析仪（TG/DTA ）、傅立叶变换红外光谱仪(FT-IR)、透射电镜 （TEM ）、扫描电镜（SEM ）等对其进行了表征。另外，以最大发射波长254 nm 的紫外光为光源，分散 红210染料为目标降解物，在反应器中评价了该催化剂的光催化活性。结果表明，纳米TiO2颗粒在涂膜 上分布相对均匀，团聚颗粒较少，且颗粒粒径约在5-10 nm左右，形貌为较规则的球形或类球形；团聚 颗粒尺寸在20-200 nm范围内。同时催化剂中有效的掺杂了硫元素，且有较高的催化活性和理想的再生 效果，具有较好的应用前景。 关键词 溶胶-凝胶；纳米二氧化钛膜催化剂；光催化反应器；分散染料 Investigation into Preparation and Photocatalytic Degradation Activity of the Nano-titanium Dioxide Film Catalyst * Qijin GENG Qingjie GUO College of Chemical Engineering, Qingdao University of Science and Technology, Key Laboratory of Clean Chemical Process, Shandong Province, P. R. 266042, China Abstract: In this article ，with Ti(OBu) as raw materials, the nanometer titanium dioxides film catalysts were 4 prepared by sol-gel preparation and rotation coating methods on inner wall of the photocatalytic reactor. These catalysts were characterized by TG/DTA, FT-IR, TEM, SEM, respectively. In addition, the photocatalytic activity and regeneration was evaluated by photocatalytic degradation of dispersing dyestuff red 210 under UV-light with the maximum wavelength at 254 nm. The results showed that this catalyst dispersed evenly on the reactor wall film, which has a high photocatalytic degradation and an excellent regeneration activity, therefore, it has a prosperous trend in applied field. Keywords: Sol-gel; Nano-titanium dioxide film catalyst; Photocatalytic reactor; Dispersing dyestuff. *联系人：郭庆杰(1967-)，男，教授，博士生导师。E–mail ：qj_guo@, 0532。第一作者: 耿启金 (1969—) ， 男，讲师，博士研究生, jngengqijin@, 0532-84022