钒磷酸钇论文：稀土掺杂钒磷酸钇低维纳米材料的制备及发光性质.docVIP

钒磷酸钇论文：稀土掺杂钒磷酸钇低维纳米材料的制备及发光性质 【中文摘要】以稀土钒酸盐为基质的纳米荧光材料在紫外光激发下具有很好的发光性质和热稳定性,引起了人们的广泛关注。通过PO43-部分替代VO43-,荧光体的发光性质得到了进一步的改善。YPxV1-xO4:Eu3+被证明是潜在的PDP红粉材料,而Dy3+掺杂的YPxV1-xO4由于同时具有黄蓝发射峰而成为潜在的白色荧光材料。尽管对于稀土钒酸盐和钒磷酸盐的研究较多,但是通过燃烧法和静电纺丝法来制备该体系的研究还很少见,这将是一个有意义的研究课题。本文中利用燃烧法和静电纺丝法,分别合成出YPxV1-xO4:Dy3+纳米粒子和YPxV1-xO4:Dy3+、YPxV1-xO4:Eu3+纳米纤维和纳米带。通过TG-DTA、XRD、FTIR、FESEM和荧光光谱等技术对样品进行了表征,得到了一些有意义的结果。(1)采用燃烧法合成了YPxV1-xO4:Dy3+(X=0,0.2,0.4,0.6,0.8,1)球形纳米粒子,粒子分散性良好,平均直径为61nm,随着X值的增加,样品的平均晶粒尺寸下降,Dy3+的Y/B比值与发光强度逐渐下降。当X0.6时,可以观察到VO43-的发射,随着X增大而增强。当0.20.6时,可以观察到VO43-的发射,随着X增大而增强。此外,当0.2≤X≤0.4时,YPxV1-xO4:Dy3+发出较好的白光；X越低,YPxV1-xO4:Eu3+的色纯度越好。 【英文摘要】Rare earth ions activated YVO4 phosphors have received more and more attention in recent years owing to their high luminescent intensities and stability under UV excitation. By partial replacement of VO43- ions with PO43- ions, a new series of Ln-doped yttrium phosphate-vanadates (YPxV1-xO4) have been obtained with better luminescent properties. YPxV1-xO4:Eu3+ has been proved to be a new potential red phosphor for plasma display panel (PDP). Dy3+-doped YPxV1-xO4 is a potential white phosphor due to its yellow and blue emissions. Although the investigations on YVO4:Ln and YPxV1-xO4:Ln phosphors are extensive, little study has been reported on synthesis of them by combustion method and electrospinning process. It will be an important and novel research subject.In this work, YPxV1-xO4:Dy3+ nanomaterials were synthesized by combustion method. YPxV1-xO4:Dy3+, YPxV1-xO4:Eu3+ nanofibers and nanobelts were prepared by a combination method of sol-gel process and electrospinning. X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), thermogravimetric-differential thermal analysis (TG-DTA), scanning electron microscopy (SEM), and photoluminescence (PL) were used to characterize the resulting samples. The meaningful results are indicated as below:(1) YPxV1-xO4:Dy3+ (X=0,0.2,0.4,0.6,0.8,1) phosphors were prepared by combustion method. The results