基于蒽和芘分子封端芴-芳胺衍生物可溶液加工蓝光材料合成与光电性质.pdfVIP

物理化学学报(Wuli Huaxue Xuebao) July Acta Phys. -Chim. Sin. 2014, 30 (7), 1341-1346 1341 [Article] doi: 10.3866/PKU.WHXB201405041 基于蒽/芘分子封端的芴-芳胺衍生物的可溶液加工的蓝光材料的合成 与光电性质 欧阳密 吴启超 余振伟 李洪飞 张 诚* (浙江工业大学化工学院, 杭州310014) 摘要: 合成了两类分别基于芘和蒽封端的芴-芳胺衍生物(FAn, FPy)的新型可溶液加工蓝色发光分子, 两种材 料均溶于常规的有机溶剂, 并且可以旋涂成膜. 通过紫外-可见光谱和荧光光谱对其在溶液中和固态薄膜下的 光学性能进行了表征, 发现这两类分子在固态下发射峰分别位于449 和465 nm, 属于蓝色发光材料. 并通过循 环伏安法表征了其电化学性能, 计算得出FAn 和FPy 的最高占据分子轨道(HOMO)能级分别为-5.37 和-5.36 eV. 结果表明N- 己基二苯胺的引入有效阻止了分子在固态下的平面堆积, 抑制了长波发射, 并且提高了分子 HOMO 能级, 改善了空穴注入能力. 差示扫描量热法(DSC)和热重分析(TGA)测试表明这两类化合物均显示出 良好的热稳定性, 其中FAn 的玻璃化转变温度和热分解温度分别达到了207 和439 °C. 良好的性能使得这两类 材料成为一种潜在的可溶液加工的蓝光材料. 关键词: 溶液加工; 蓝色荧光; 空穴注入; 芴; 芘; 蒽 中图分类号: O644 Synthesis and Photoelectrical Properties of Two Potential Solution- Processed Blue Fluorescent Emitters Based on Fluorene-Arylamine Derivatives End-Capped with Anthracene/Pyrene Molecules OUYANG Mi WU Qi-Chao YU Zhen-Wei LI Hong-Fei ZHANG Cheng* (College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, P. R. China) Abstract: Two novel potential solution-processed blue fluorescent emitters composed of a core fluorene- diphenylamine unit capped with either anthracene (FAn) or pyrene (FPy) were synthesized and characterized. They were both soluble in common organic solvents and solutions gave smooth films after spin coating. Their optical properties in solution and in the film were investigated by UV-visible and photoluminescence (PL) spectroscopy. The PL emission maximum