重铬酸钾氧化_硫酸亚铁滴定法快速测定海洋沉积物中有机碳_刘昌岭.pdfVIP

26 3 V o l. 26, N o. 3 2007 6 RO CK AND M INERAL ANALY SIS June, 2007 : 0254 - 5357 ( 2007 03- 0205- 04 重铬酸钾氧化- 硫酸亚铁滴定法快速测定 海洋沉积物中有机碳 刘昌岭, 朱志刚, 贺行良, 张 波, 夏 宁 (, 266071 : 采用重铬酸钾氧化- 硫酸亚铁滴定法, 建立了一 快速测定海洋沉积物中有机碳含 量的方法选择了海洋沉积物样品的粒径大小干燥温度和干燥时间, 探讨了催化剂的用量及氯 离子的干扰和消除方法方法是对国标 GB /T 17 378. 5) 1998的合理改进, 大大地缩短了实验流 程, 降低了测定成本对国家标准物质进行测定, 并与仪器分析结果比对, 证明本法可靠准确 : 氧化滴定法; 有机碳; 快速测定; 海洋沉积物 : O655. 23; O613. 71; P736. 211 : B Rapid D eterm ination of Organic Carbon in M arine Sedim ent Samples by Potassium D ichromate Oxidation-Ferrous Sulphate T itrim etry L IU Chang-ling, ZH U Zh i-g ang, H E X ing-liang, ZHAN G B o, X IA N ing ( Q ingdao Institute o f M a rine Geo logy, Q ingdao 266071, C hina) Abstract A rap id m ethod for the determ inat ion of organic carbon in m arine sed mi ents by po tassium d ichrom ate ox idation-ferrou s sulphate titrmi etry w as deve loped. Som e mi po rtant ana lytical param eters, such as sam p le g rain - size, dry ing tem perature and tmi e, w ere optmi ized. T he dosage o f cata lyst as w ell as the interference from C l and the interference elmi ination w ere also d iscu ssed. T h is m ethod, derived from the N ational Standard ( GB /T 17 378. 5) 1998 and m od ified reasonably, can g reat ly shorten the expermi ental procedure and reduce the cost. The accuracy and reliability o f th is m ethod have been proved by analysis of N ationa l Standard Re ference sam ples and com parison w ith other ana ly tica l m ethods. K ey w ord s ox idation t itrmi etry; o