三嵌段共聚物PAN_b_PEG_b_PAN合成及自组装行为研究.pdfVIP

2006 64 Vol. 64, 2006 24 , ACTA CHIMICA SINICA No. 24, · · PAN-b-PEG-b-PAN * ( 710062) (ATRP)-b--b- (PAN-b-PEG-b-PAN). 1H NMR, FTIR, (GPC) TG DTA ; (TEM)(DLS) P(AN)27-b-P(EG)45-b-P(AN)27 . , P(AN)27-b-P(EG)45-b-P(AN)27 P(EG), PEG . , , DLS TEM , (cmc)4.46 104 g•L1. ; ; Study on Synthesis of PAN-b-PEG-b-PAN Triblock Copolymer and the Self-assembly Behaviors LEI, Zhong-Li* LIU, Ya-Lan (Key Laboratory for Macromolecular Science of Shaanxi Province, School of Chemistry and Materials Science, Shaanxi Normal University, Xian 710062) Abstract Atom transfer radical polymerization (ATRP) was used to synthesize the block copolymers of poly(acrylonitrile)-b-poly(ethylene-glycol)-b-poly(acrylonitrile) (PAN-b-PEG-b-PAN). The copolymers 1 were characterized by using H NMR, FTIR spectra and gel permeation chromatography (GPC). The ther- mostabilities of these copolymers were investigated by TG and DTA. Transmission electron microscope (TEM), fluorescence spectroscopy and dynamic light scattering (DLS) were used for the investigation of the self-assembly of the copolymers. Comparing the thermostabilities of PEG, the thermostabilities of P(AN)27-b-P(EG)45-b-P(AN)27 were improved and the exothermic peak position of the copolymers had no obvious changes when PEG blocks existed. The results of the TEM observations showed that polymeric mi- celles of P(AN)27-b-P