多金属氧酸盐光催化降解有机磷农药的研究.pdfVIP

安徽农业科学 , Journal of Anhu i A gri. Sci. 2009 , 37 ( 10) : 4614 - 4615 , 4624 责任编辑 　常俊香 　责任校对 　夏蓉 多金属氧酸盐光催化降解有机磷农药的研究 马凤霞 ,薛晓丽 ,王 丰 　(吉林农业科技学院文理学院 ,吉林吉林 132 10 1) α 摘要　考察了多金属氧酸盐在紫外光照下对有机磷农药的光催化降解行为 。结果表明, H4 SiW 12 O40光催化降解对硫磷的效果最佳 。 μ α 4 1. 5 mol/ l对硫磷溶液最佳降解条件为 : H4 SiW 12 O40用量 0. 7 g/L , pH 值 2. 0, 500 W 的荧光灯照射 60 m in,对硫磷降解率达到92. 5% 。 关键词　多金属氧酸盐;光催化降解 ;有机磷农药 ( ) 中图分类号　O611. 5　　文献标识码　A　　文章编号　0517 - 6611 2009 10 - 04614 - 02 Study on Photo Ca ta lyz ing D egrada tion of O rganophosphorous Pestic ides by Polyoxom eta la tes ( ) M A Fengx ia et a l　 Co llege of A rts and Science, J ilin A gricu ltural Science and Technology Un iversity, J ilin , J ilin 132 10 1 A b stract　The photo catalyzing degradation condition of organopho sphorou s p esticide s by po lyoxom etalate s under UV light was investigated. α The re su lts showed that the photo catalyzing degradation effect of H4 SiW 12 O40 on p arath ion wa s the be st. The op timum degradation condition μ α of 4 1. 5 mol/L p arath ion was that H4 SiW 12 O40 do sage of 0. 7 g /L , pH value of 2. 0 and irradiation tim e of 60 m in w ith 500 W m ercury lamp. Under th is condition , the degradation rate of p arath ion wa s 92. 5%. Key words　Po lyoxom etalates; Photocatalyzing degradation; O rganopho sphorou s p esticide s 　　杀虫剂中有机磷农药占 70% ,至今仍是世界上生产和