新型核壳结构的Fe3O4MnCO3+Li2CO3纳米粒子的制备【毕业论文】.docVIP

本科毕业论文 （20 届） 新型核壳结构的Fe3O4/MnCO3+Li2CO3纳米粒子的制备 专业：化学工程与工艺 [摘要] 采用多通道撞击流反应器首先制备出纳米核壳结构的Fe3O4/MnCO3覆合凝胶粒子，再通过液相沉积和浸渍的方法在该凝胶粒子表面包覆一层复合锂化合物，形成具有三明治结构的覆合纳米粒子。在优化Fe3O4/MnCO3覆合凝胶过程中主要考察了撞击强度、前躯体浓度、支流道数对包覆效果的影响。通过液相沉积或浸渍的方法包覆的锂化合物有Li2CO3、LiOH、LiNO3、Li2CO3+LiNO3BET、TG、XRD、TEM、SEM、AAS、VSMLi2CO3+LiNO3，所得磁性纳米锂离子筛前躯体的平均粒径约为40nm，比表面积达到63.67m2/g，比饱和磁化强度(δs)为27.581 emu/g，磁矫顽力(Hci)为138.64 G。锂含量高达50mg/g以上，产物经热处理和酸浸脱锂后锰溶损率为1.96%，铁溶损率为2.26%。该产物具有工艺简单，制备成本低，产量高等特点，工业化前景极大。 [关键词] 反应工程；纳米结构；包覆；膜；锂；四氧化三铁 Preparation of Novel Core-shell Nanostructured Fe3O4/MnCO3+Li2CO3 [Abstract] Core-shell nanostructured Fe3O4/MnCO3 gels were first synthesized by a newly-designed multi-channel impinging stream reactor, followed by coating Li2CO3+ LiNO3 to form sandwich-structured Fe3O4/MnCO3/Li2CO3+LiNO3 nano powders, which were heated at 673 K to prepare nano Fe3O4/LixMnyO4 powders. Factors affecting the explosive nucleation and film-coating processes as well as the properties of nano Fe3O4/MnCO3 gels such as impinging intensity, precursor concentration and the number of branch channel were mainly studied to achieve the required products. Moreover, several lithium materials such as Li2CO3, LiOH, LiNO3 and Li2CO3+LiNO3 were also investigated. The products in every step were characterized by BET, TG, XRD, TEM, SEM, AAS, VSM, etc. The results showed that the optimum film materials were the composite nanofilm of Li2CO3+LiNO3. The as-prepared Li-type magnetic lithium ion sieves has a specific area of 63.67m2/g, specific magnetism (δs) of 27.581 emu/g and coercive intensity (Hci) of 138.64 G. The mean particle size was about 40 nm. The lithium content was more than 50mg/g. The solution-loss rates of manganese and iron were 1.96% and 2.26%, respectively. The whole synthesizing route is a straightforword process with a high productivity and low production cost, which implies the promising route to be industialized. 动词 represent stand for some point of view 副词 on behalf of in the name of [Key words] Reaction