助剂对CuO－CeO2催化剂VOC催化燃烧性能的影响研究【毕业论文】.doc

本科毕业论文 （20 届） 助剂对CuO－CeO2催化剂VOC催化燃烧性能的影响研究 专业：化学工程与工艺 摘要 在现有的众多处理技术中，催化燃烧法是消除挥发性有机化合物(VOCs)污染最有效方法之一，具有设备简单，能耗低，消除效果好等特点。而催化剂是催化燃烧法消除VOCs的关键技术。通过研究发现，一般在催化剂中加入助剂，或多或少都会对催化剂的活性产生影响，所以我打算在这次实验中加入相同含量的不同助剂来测试CuO－CeO2的活性，从中挑选出最有效的助剂，再通过改变它的含量来使催化剂达到最佳效果。 采用浸渍法在Cu-CeO2载体表面涂覆了同样含量金属化合物，再通过马沸炉400℃焙烧，使金属氧化物覆盖到Cu-CeO2载体上。将制备出来的催化剂通过VOCs处理，从中选出催化效果最好的，在对其进行进一步的研究。通过改变这种助剂在Cu-CeO2催化剂中的不同含量，来最终确定对CuO－CeO2催化效果提高最好的助剂及其含量。 本研究基于Cu-CeO2催化剂优良的VOCs的催化燃烧性能，用金属氧化物助剂制备负载Cu-CeO2的燃烧催化剂，使其具有较高的活性和热稳定性。并用XRD、TPR、BET等方法对催化剂进行了详细的表征。 关键词：浸渍法；XRD;BET;TPR;载体;活性;热稳定性 ABSTRACT In the existing number of processing, the law is to act as volatile organic compounds (VOCs) pollution, one of the most effective method of device is simple, low energy consumption, the effect is good as a catalyst. but it is the law to eliminate vocs a key technique. through study found that the catalyst to the catalyst, additive used in the activity influence。So I'm going to join in the experiment in the same content of the additive used to test Cu-CeO2 activity, and choose the most effective additive used, by changing its contents to make a catalyst to get best effect. Adopt maceration the Cu-CeO2 carrier on the surface with the same level of metal; then through furnace 400 ℃ firing, the metal oxides over Cu-CeO2 carrier. the preparation of the catalyst and out through vocs catalytic effect the best in a further study.By changing the additive used the Cu-CeO2 a catalyst in content, and finally determined to Cu-CeO2 catalytic effect of the additive used and its content. Based on this research Cu-CeO2 a catalyst for the benefit of the performance of the catalytic vocs, using metal oxides additive used the preparation of the load Cu-CeO2 the burning of the catalyst, it can provide a more active and stability. with xrd, tpr, bet on a catalyst for the index. Keywords ：maceration law;xrd; bet; tpr; carrier ;activity ;hot stability 目录 中文摘要 I 英文摘要 II 1前言 1 1.1 挥发性有机物的概念及污染现状 1 1.2 主题 1 1.2.3 催化燃烧特点 1 1.3 VOC催化剂研究进展 1 1