【精品】【论文资料】 X253-定位锌结晶釉析晶动力学分析（审核通过稿）.docVIP

定位锌结晶釉的析晶动力学分析 刘 洋，唐大海，李志科，李月明 (景德镇陶瓷学院材料学院景德镇 333403) ：本文以ZnO作为定位结晶剂制备了ZnSiO3结晶釉，测试了在不同析晶保温时间下釉面晶花大小根据结晶动力学理论，对结晶釉中ZnSiO3晶的生长规律和结晶机理进行了分析探讨结果表明：析晶保温时间超过30min，晶形成速率随时间而显著提高，并在45min到60min范围内达到最大值；析晶保温时间超过90min，晶形成速率随时间而快速下降析晶保温时间超过150min，晶基本上不再生长，形成达到稳定值。采用ZnO作定位晶种的釉面结晶稳定性好，釉面晶花与保温时间符合S型生长曲线关系，可用Logistic拟合：锌结晶釉；定位结晶；结晶动力学；晶体形成速率kinetics analysis of zinc crystalline glaze using seed crystal Liu Yang, Tang Da-hai, Li Zhi-ke, Li Yue-ming (School of Materials Science and Engineering, Jingdezhen Ceramic Institute, Jingdezhen, 333403) Abstract：Zinc silicate crystalline glaze was prepared zinc oxide as seed crystal. The crystal size of zinc silicate crystalline glaze samples under different soaking time was measured. The mechanism of zinc silicate crystal growth and crystallization was discussed according to the crystal dynamics theory. The results showed that the crystal formation rate increased significantly with time when the soaking time was over 30 min, and the crystal formation rate reached the maximum value when the soaking time was in the range of 45~60 min. When the soaking time was over 90 min, the crystal formation rate markedly decreased with time, and the crystal growth rate basically reached a stable value when the soaking time was over 150 min. Using zinc oxide as seed crystal, zinc crystalline glaze with good performances and stability can be prepared. The relationship between the crystal size and soaking time fits S-type growing curve and can be simulated by Logistic function. This study provides the reference to the realization of controllable growth of zinc crystalline glaze. Key words：inc crystalline glaze; Seed crystallization; Crystal dynamics theory; Crystal formation rate 1 引 言 结晶釉是一种具有绚丽色彩，别具的艺术釉[1]。其晶形变幻自然、晶花绚丽多姿，与色釉结合能够达到艺术效果。锌结晶釉是以ZnO为结晶剂，因其结晶性能好，晶花呈大型扇形纹样等特点越来越受到人们的欢迎。锌结晶釉与一般结晶釉结晶原理大致相同，其晶核来源于釉熔体中加入的晶核剂在冷却过程中过饱和条件下形成的晶核[2]。这些晶核是晶体发育长大形成晶花的基础但其结晶的数量与分布是自由的, 具有偶然性和变异性，并且晶花之间还可能出现重叠或者晶花的形状生长的不完整，有缺陷[3]。通过对结晶动力学的研究可以掌握特定温度下晶核的成核速率和晶体的生长速率，控制晶花的数量大小