3.6 双原子分子结构（The structure of diatomic molecule ）.pptVIP

3.6 双原子分子结构(The structure of diatomic molecule ) 3.6.1 同核双原子分子结构 (The structure of homonuclear diatomic molecule ) O2：8+8=16 F2：9+9=18 反磁 diamagnetic 键级=1 bond order=1 B2: 5+5=10 C2: 6+6=12  等电子原理 某些异核双原子分子与同核双原子分子电子总数相同，周期表位置相近，它们的分子轨道的电子排布也大致相同，即等电子原理。 isoelectronic principle Some heteronuclear diatomic molecules and homonuclear diatomic molecules have the same total number of electrons, and the positions in the periodic table are close, and their electron configuration of molecular orbital is roughly same, namely, isoelectronic principle. CO-N2 等电子体 14个电子 HF 配位化合物