水体冻结过程中卤乙酸前体物在水_冰体系中分配的研究.pdfVIP

中国环境科学 2014,34(11) ：2773~2780 China Environmental Science 水体冻结过程中卤乙酸前体物在水-冰体系中的分配研究 * 薛 爽,陈 静,铁 梅 ,惠秀娟,张丽娜,张 营 (辽宁大学环境学院,辽宁 沈阳 110036) 摘要：通过室内模拟试验,研究了水体冻结过程中,水体中溶解性有机物(DOM)和卤乙酸前体物在水-冰体系中的分配规律.按照 DOM 在 XAD 树脂上的吸附特性将其分为 5 个部分:疏水性有机酸(HPO-A),疏水性中性有机物(HPO-N),过渡亲水性有机酸(TPI-A),过渡亲水性中 性有机物(TPI-N)和亲水性有机物(HPI).结果表明:在水体冻结过程中,5 种 DOM 组分在水相中的 DOC 浓度均随冷冻时间的增长而增加,呈 现冷冻浓缩效应.与溶解性有机碳(DOC)所表征的整体有机物相比,5 种 DOM 组分中的卤乙酸(HAAs)前体物更倾向于停留在水相中浓缩. 在 5 种 DOM 组分中,HPI 是主要的 HAAs 前体物.5 种 DOM 组分在未冻结水中的 UV-254 与 HAAFP 均表现出一定相关性,其中 HPO-A, TPI-A 和 HPI 的 UV-254 与 HAAFP 达到极显著水平.然而在融冰水中,这 5 种 DOM 组分的 UV-254 与 HAAFP 的相关性均不显著. 关键词：冻结；溶解性有机物；分级；紫外光谱；卤乙酸前体物 中图分类号：X703,TU992 文献标识码：A 文章编号：1000-6923(2014)11-2773-08 Ratio of haloacetic acids precursor in water-ice system during the freezing processes of water. XUE Shuang, CHEN * Jing, TIE Mei , HUI Xiu-juan, ZHANG Li-na, ZHANG Ying (School of Environmental Science, Liaoning University, Shenyang 110036, China). China Environmental Scenice, 2014,34(11)：2773~2780 Abstract ：It was studied the partition of dissolved organic matter (DOM) fractions and haloacetic acids (HAAs) precursors in water-ice system during the freezing processes of water by the indoor simulating tests. DOM was fractionated using XAD resins into five fractions: hydrophobic acid (HPO-A), hydrophobic neutral (HPO-N), transphilic acid (TPI-A), transphilic neutral (TPI-N) and hydrophilic fraction (HPI). The results showed that the freezing rate of water samples containing acid fractions wove higher than samples containing neutral fractions. DOC concentrations for five DOM fractions in liquid phase increased with freezing time, presenting the freeze-concentration effect, during the freezing processes of