胶原纤维固化单宁及其对Cu2+吸附.pdfVIP

___________________________________________________________________________ 胶原纤维固化单宁及其对Cu2+ 的吸附 廖学品， 邓慧， 陆忠兵， 石碧 ( 四川大学 皮革化学与工程教育部重点实验室，成都 610065) 摘要：以胶原纤维为基质，通过交联剂将黑荆树皮单宁、落叶松单宁和毛杨梅单宁固化在胶原纤 维上制备吸附材料。实验表明，三种固化单宁对Cu2+ 的吸附平衡均符合Freundlich 方程，其吸附 容量大小顺序为固化毛杨梅单宁固化黑荆树皮单宁固化落叶松单宁。进一步研究了固化黑荆树 皮单宁的吸附动力学、吸附柱动力学，以及温 、pH 值等对吸附平衡的影响。结果表明，温 对 吸附平衡的影响不明显，但pH 值对吸附平衡有较大影响，在适当范围内提高pH 值，会增加平衡 吸附量；吸附动力学可用拟二级速 方程来描述，当吸附温度≧318 K 时，由拟二级速 方程计 算所得到的平衡吸附量与实测的平衡吸附量非常吻合。固化单宁具有良好的柱动力学特性，吸附 柱极易再生并且能循环使用，吸附过程极有可能是在材料的表面进行。 关键词：胶原纤维；固化单宁；Cu2+ ；吸附；环境污染防治 中图分类号：TQ351.5; x5 文献标识码 A 文章编号：0253-2417(2003)04- COLLAGEN IMMOBILIZED TANNINS AND 2+ THEIR ADSORPTION FOR Cu LIAO Xue-pin， DENG Hui， LU Zhong-bing， SHI Bi (The Key Laboratory of Leather Chemistry and Engineering of Ministry of Education, Sichuan University, Chengd u 610065 China) Abstract: Using collagen fibre as matrices, the immobilized tannins adsorbents based on black wattle, larch and my rtan tannins were prepared through crosslinking reaction. As novel adsorbents ，their ability 2+ of recovering Cu from waste water was studied. Experiments showed that adsorption isotherms of 2+ immobilized tannins for Cu could be described by Freundlich model and their adsorption capacities were in the sequence of immobilized myrtan tannin immobilized black wattle tannins immobilized larch tannin. Furthermore, adsorption characteristics of immobilized black wattle tannin that has higher thermal stability were investigated in details. It was found that influence of temperature on adsorption 收稿日期：2003-03-31 基金项目：中国高校博士点基金资助项目(200206 10010) 作者简介： 学品( 1963-)，男，四川乐至人，教授，研究方向：植物单宁化学及磷酸 材料。 通讯联系人，E-mail: shibi@