金刚烷胺制药胺化废水与溴化废水的中和-络合萃取处理.pdfVIP

中国环境科学 2014,34(10) ：2522~2527 China Environmental Science 金刚烷胺制药胺化废水与溴化废水的中和-络合萃取处理 宋永会 1,2*,魏 健 1,2,马印臣 1,2, 曾 萍 1,2 (1. 中国环境科学研究院,环境基准与风险评估国家重点实验室,北京 100012；2. 中国环境科学研究院,城市水环境科技创新基地,北京 100012) 摘要：考察了两种废水中和反应过程对污染物的去除效果,然后采用 P204/正辛醇复配萃取剂对废水进行络合萃取处理.结果表明,采用溴化 废水中和滴定胺化废水可以大幅消减废水中污染物,避免后续萃取过程中的乳化现象;在 pH 值为 8.0,油/水相比为 1:1 的条件下,P204 :正辛醇 =3:2 的复配萃取剂对废水中 TOC 和金刚烷胺的单级萃取效率分别为 49.6%和 99.5%;多级萃取对 TOC 去除率没有明显提高;以 2.0mol/L 的 HCl 溶液为反萃取剂,在水/油相比为 1:1 条件下,可以将 47.5% 的金刚烷胺从负载有机相中反萃分离,回收得到的金刚烷胺盐酸溶液可以 回用,再生后的萃取剂可以多次重复使用. 关键词：金刚烷胺；制药废水；络合萃取；反萃取废水处理 中图分类号：X703 文献标识码：A 文章编号：1000-6923(2014)10-2522-06 Neutralization-complex extraction treatment of amantadine pharmaceutical amination wastewater and bromination wastewater. SONG Yong-hui1,2*, WEI Jian1,2, MA Yin-chen1,2, ZENG Ping1,2 (1.State Key Laboratory of Environmental Criteria and Risk Assessment, Chinese Research Academy of Environmental Sciences, Beijing 100012, China；2.Department of Urban Water Environmental Research, Chinese Research Academy of Environmental Sciences, Beijing 100012, China). China Environmental Science, 2014,34(10)：2522~2527 Abstract ：Influences of neutralization process on pollutants removal of the two wastewaters were investigated firstly. Then the complex extraction of the neutralized wastewater was carried out by using P204 as the extractant and octanol as the diluent. The results showed that the neutralization process could highly remove pollutants in the wastewater and avoid emulsification in the following complex extraction; Under the conditions of pH value 8.0, oil-water ratio 1:1and P204 :octanol=3:2, the single stage extraction efficiency of TOC and amantadine was 49.6% and 99.5%, respectively; Multi-stage extraction had no significant improvement on TOC removal; As stripping agent HCl solution of 2.0mol/L was used wi