双亲性嵌段共聚物胶束形貌调控研究梅爱雄.pdfVIP

第21 卷 第 10 期 Vol. 21No. 10 2009 年 10 月 PROGRESS IN CHEMISTRY Oct. , 2009 / 双亲性0嵌段共聚物胶束形貌调控的研究* 梅爱雄 杨 雍 徐君庭 杜滨阳* * ( 浙江大学高分子科学与工程学系 高分子合成与功能构造教育 重点实验室 杭州310027) 本文综述了在选择性溶剂中影响/ 双亲性0 嵌段共聚物胶束行为和胶束形貌的主要因素, 包括 溶液温度、选择性溶剂种类、嵌段长度、链段结晶、链段与溶剂间氢键作用以及共聚物浓度等对胶束最终形貌 产生影响的因素; 系统介绍了对嵌段共聚物胶束形貌进行调控的实验方法; 在此同时介绍了对环境刺激如温 度和pH 变化等具有响应性能的/ 双亲性0 嵌段共聚物在选择性溶剂中胶束行为研究的最新进展; 最后提出 了该研究领域目前存在的问题和今后的可能发展方向。 / 双亲性0嵌段共聚物 胶束 形貌调控 : O631; TB324; TB383 : A :(2009) 1022188211 The Morphological Study of Amphiphilic Block Copolymer Micelles * * Mei Aixiong Yang Yong Xu Junting Du Binyang (Key La oratory ofMacromolecular Synthesis and Functionalization, Ministry of Education, Department of Polymer Science Engineering, Zhejiang University, Hangzhou 310027, China) Abstract In this paper, the main factors which may influence the micelle morphology and ehavior of amphiphilic lock copolymers in selective solvents are reviewed. These factors mainly include the solution temperature, the type of selective solvents, the lengths of locks, the crystalline lock, the hydrogen2 ond interaction etween the locks and the solvent as well as the concentration of the lock copolymers. The experimental methods for controlling the micelle morphology of amphiphilic lock copolymers in selective solvents are then summarized. The recent advances in the micellar ehaviors of a special type of amphiphilic lock copolymers in selective solvents, which are capa le to response to the external stimu