热解终温对污泥热解产物分布及特性的影响.docVIP

温度对污泥热解产物及特性的影响 高现文1 李海英2 单春贤1 郝建新1 高鹤明1 （1. 江苏大学能源与动力工程学院,江苏 镇江 212013;2. 河北理工大学冶金与能源学院,河北 唐山 063009） 摘要：用直径为200mm的外热式固定床反应器,以唐山西郊污水处理厂剩余污泥为实验物料,在终温为250℃-700℃并在初期通以氮气的情况下,对污泥的热解产物分布及特性进行了研究.实验表明：在物料成分和其它条件不变的情况下,随着热解终温的提高,热解反应所需时间缩短;热解气和热解焦油的总产率增加;焦炭产量减少;热解焦炭的工业分析表明,随热解终温的升高挥发分减少、固定炭和灰分增加;热解焦油的热值在10－43MJ/Kg之间;焦炭的热值10－24MJ/Kg之间.为不同工业需求制定不同的热解温度提供了依据. 关键词：污泥热解;热解产物特性;产率;热解终温 中图分类号：X705 文献标识码：A The effect of temperature on products and Characteristics of sludge’s pyrolysis Gao Xianwen1 Li Haiying2 Shan Chunxian1 Hao Jianxin1 Gao Heming1 1- School of Energy and Power Engineering, Jiangsu University. (Zhenjiang, Jiangsu 212013, China 2- School of Maetallurgy and Energy , Hebei Polytechnic University. (Tangshan , Hebei 063009,china) Abstract: The equipment of the experiment is external-heat fixed bed reactor with a diameter of 200 mm. The material is the deposit sludge, collected from a sewage disposal plant in the western suburb of Tangshan city. The ultimate temperature ranks from 250 ℃ to 700 ℃, and at the beginning of each experiment, N2 is brought in. The distribution of pyrolysis products and their characteristics are analyzed. This experiment shows that: when the same material is used and other conditions are not changed, the time of the pyrolysis reaction is becoming shorter as the ultimate temperature increases; the productive rares of pyrolysis gas and pyrolysis tar are both increased; the output of coke is decreased; The calorific value of pyrolysis tar is at 10－43MJ/Kg; and the calorific value of pyrolysis coke is at 10－24MJ/Kg. Offer basis for the choice of ultimate temperature to meet different need and the experiments of pyrolysis. Keywords: Sludge prolysis;The distribution of products;Temperature 引言 污泥是城市污水处理及废水处理不可避免的副产品,且产量巨大.据估计,全世界一年产生的干污泥量达1亿吨,而我国约2×105吨[1].随着人类环保意识的提高和全球资源逐渐匮乏,污泥的管理和资源化利用已成为目前一个世界性的能源、社会和环境问题. 在我国长期以来存在着重废水处理,轻污泥处理的倾向.在已建成的污水处理厂中,90％ 1－温控仪 2－热电偶 3－加热炉 4－反应器 5－充氮管6－收集器 7－温度计 8－换热器 9－U型管差压计 10－取气口11－气体流量计