CODCr的分光光度法测定及综合效益分析.docVIP

CODCr的分光光度法测定及综合效益分析 陈　玲,程五良,蒋柱武,赵建夫 (同济大学污染控制与资源化研究国家重点实验室,上海　200092) 摘要:对CODCr分光光度法的准确性及方法精度进行了系统的研究,着重考察了分光光度法在工业废水和生活污水CODCr测定中应用的可行性,研究中发现测试结果存在对所选标准物的依赖性问题.根据实际废水复杂性特点,提出将高浓度废水作为综合标准母液,依次稀释并用传统标准法测定其质量浓度ρC O DCr值,并测定其在610 nm波长处的吸光度值,绘制出特种废水专用的工作曲线的改进方法.试验结果表明:改进后的分光光度法重现性好,与传统标准法有很好的一致性.比较了分光光度法与传统标准法的经济效益及环境效益,在单次测试 中,分光光度法测试成本约为传统标准法的50%,其潜在的二次污染比传统标准法低得多.因此,经改进的CODCr分光光度法具有良好的应用前景,值得推广普及. 关键词: CODCr;分光光度法;经济效益;环境效益 中图分类号: X 132　　　文献标识码: A　　　　文章编号: 0253-374X(2002)06-0723-05 Determination of CODCrSpectrophotometry and Application Assessment CHEN Ling, CHENG Wu-liang, JIANG Zhu-wu, ZHAO Jian-fu (State Key Laboratory of Pollution Control and Resources Reuse,Tongji University,Shanghai 200092,China) Abstract: Experimental studies on the CODCr Spectrophotometric Method and its application in industrial wastewater and domestic water were conducted.It is found that the dependency of the results on the selected standard substance that was used to build the standard curve exists. A modifying way was first proposed, that is to select a wastewater-self with higher concentration of CODCr as the standard substance, and to dilute it to a series of different concentrations of standard solution, so the special working curve should be obtained. And the results with lower derivation have been obtained. The modified CODCr spectrophotometry with the traditional standard method was compared, and the consistency of results between above two methods was obtained. Besides, the cost and the environmental impact of two methods respectively discharging pollutants in one determining run have been discussed and analyzed. It is shown that modified CODCr spectrophotometry is more economical,about 50% cost of the traditional method, and the second discharged pollutants is lower. Key words: CODCr; spectrophotometry; economic efficiency; environmental effciency 化学需氧量(chemical oxidation demand, COD)是国内外环境领域评价水体污染程度的重要指标.由于传统的重铬酸钾法(CODCr)[1,2]分析周期长,能耗高,所使用的银盐、汞盐及铬盐等会造成二次污染,近年来已有被迅速发展起来的分光光度法取代之