电位法测氢氧化钠浓度 英文版报告.docVIP

Lab Report Determination of corsistency of NaOH Instrumetal Analysis Tang Denghui Ma conbin Class 1026 Mujor Eevironmental Rrotection Dec 7th 2011 Objective：（a）To understand the characteristic basic principles，calculation and application of potetiometry. （b）To understand determination principle and calculation method of PH，the effect of total ionic strength adjustment buffer，standard addition methods. （c）To master electrochemical sensor is computation，determination of equivalence point and its computation of potentiometric of computation of potentiometric titration. Theory：To use the PH meter which named starter 3c determine the result of the standard solution of Hydroxide cunknown consistency)，compietely. Finally ,to know the consistency by Second Devivution. Procedure：(a)Preparaed the standard sdution of Hydrochloric Acid (b)Took 4.2ml from 12 mol/L standard solution of Hydrochloric Acid water. (c)Took sonce sodium Carbonic to standardize and got out some datas as Tab.1-1 Tab.1-1 m Na2Co3 g v Hcl ml C Hcl mol/L C2 Hcl mol/L 0.1089 23.52 0.0874 0.0875 0.1163 25.02 0.0877 0.1185 25.6 0.0873 (d)Turn the starter 3c meter to PH checking and negulaing the equipment. (e)Took25.00ml unknown constry Sodium Hydroxide solution accurately, then added 50ml Distilled water (boiling).wash the equipment carefully . (f)Let the starter 3c meter to the Sodium Hydrochloric Acid standard solution titrated the Sodium Hydrochloric titration ending up to the PH having a large change. (g)Took notes about the PH and the volume of Hydrochlorir Acid standard solution as Tab.1-2(a). Tab.1-2(a) V2 HCL VHCL PH PH/V PH2/V2 0 12.46 24.04 9.93 24.09 4.1 24.14 9.51 1 24.19 4.2 24.24 9.10 98 24.29 13.9 24.34 7.71 -65 24.39 7.4