混合厌氧消化论文：半连续餐厨垃圾与猪粪混合厌氧消化性能及动力学研究.docVIP

混合厌氧消化论文：半连续餐厨垃圾与猪粪混合厌氧消化性能及动力学研究 【中文摘要】随着国家经济发展,城市居民生活水平迅速提高,餐厨垃圾与畜禽粪便等生物质垃圾的产生量也相应剧增,在生物质垃圾处理已成为一个亟待解决的难题的同时也为资源化处理提供了丰富的物料来源。将餐厨垃圾与畜禽粪便进行混合厌氧消化,可最大程度地处理其有机组分,降低污染,又可产生沼气,回收能源,一举两得,真正实现了垃圾的无害化、资源化。本试验以餐厨垃圾与猪粪为试验原料,自制CSTR厌氧反应器(continuous stirred tank reactor,连续搅拌厌氧反应器),对半连续式进料条件下的餐厨垃圾与猪粪混合厌氧消化行为进行实验室研究。研究表明：随着有机负荷从0.5、0.75、1.OgVS/L.d递增,直至试验酸化前,pH值维持在7.1左右,VFA浓度经历了反应初期的波动后,一直稳定在900～1400 mg/L之间。消化进行到第66天时,pH降至6.7,VFA升高至5208mg/L,试验出现酸化。当有机负荷为0.75gVS/L.d时即消化第26天系统出现了最大日产气量、最大日产甲烷量和最大单位原料产气率,分别为7850mL、4357mL和0.78L/gVS。不同有机负荷下的平均甲烷含量分别为38%、51%和42%。说明负荷为0.75gVS/L.d时,厌氧消化达到平衡,试验性能最佳。通过对0.75gVS/L.d负荷下的产气过程动力学分析显示,此阶段试验厌氧消化产气过程符合一级动力学方程y,=w(1-e-k1t)=0.8035×(1-e-0.2067t),相应的动力学参数k1=0.2067。用此模型来估算该条件下的最大单位原料产气率w为0.8035 L/gVS,与试验值相对误差仅为3.0%,本研究为生物质垃圾混合厌氧消化动力学模型的构建提供了新的思路。 【英文摘要】As the economy developing and improvment of living standards, Kitchen waste, animal manure and other biomass waste will heavily increase. Through biomass waste disposal has becomed a pressing problem, it also provides a rich resource of waste recycling. The anaerobic co-digestion of kitchen waste and pig waste can not only maximize the treatment of organic components and reduce pollution, but also produce biogas and recycle energy, which makes harmless and recycling waste become a reality.In this experiment, the anaerobic co-digestion of kitchen waste and pig waste was conducted in a CSTR anaerobic reactor by a semi-continuous mode. The results showed that:with gradually increasing organic loading rate (OLR), before acidification pH value was maintained at 7.1 and VFA concentration was stable at 900-1400mg/L in addition to the fluctuation during the early experiment. To 66 days of digestion, when pH value dropped to 6.7 and VFA concentration increased to 5208mg/L, test appeared acidification. The maximum daily gas production, the maximum daily methane production and the maximum value of biogas yield under OLR of 0.75gVS/L.d were about 7850mL,4357mL and 0.78L/gVS, respectively. The average CH4 content wer