含铝化合物抑制碱硅酸反应地研究.pdfVIP

含铝化合物抑制碱硅酸反应的研究 刘志辉，兰祥辉，陆春华，许仲梓* （南京工业大学材料科学与工程学院，南京210009 ） 摘要 研究了Al(OH) 、α-Al O 等不同的含铝化合物对砾石、沸石化珍珠岩 2 种集料碱硅酸反 3 2 3 应膨胀的抑制作用，讨论了掺量、集料碱活性、碱含量对含铝化合物抑制碱硅酸反应（alkali silica reaction, ASR ）效果的影响。结果表明：含铝化合物中铝的存在方式对ASR 的抑制作用具有重要的影 响，α-Al O 对ASR膨胀是惰性的，Al(OH) 抑制ASR 的效果与Al(OH) 掺量、集料碱活性和碱含量密 2 3 3 3 切相关，Al(OH)3掺量越大，抑制效果越好；一定碱含量下，集料活性越大，抑制效果越好；对特定 集料，碱含量越小，抑制效果越好。Al(OH) 抑制ASR可能与其可以降低水泥水化产物中Ca(OH) 的 3 2 含量有关。在 80℃1mol/L的NaOH溶液养护下，掺加Al(OH)3 的水泥浆体中有水化石榴石生成。 关键词 含铝化合物 碱硅酸反应 抑制 水化石榴石 Effect of Aluminous Compounds on Inhibiting Alkali-Silica Reaction LIU Zhihui, LAN Xianghui, LU Chunhua, XU Zhongzi (College of Materials Science and Engineering, Nanjing University of Technology, Nanjing 210009) Abstract The inhibiting effect of aluminous compounds including on alkali-silica reaction(ASR) in gravel and zeolitization perlite mortars were investigated. The aluminous compounds content, the alkali reactivity of the aggregate and the alkali content will affect the inhibiting effect. Results show that the state of aluminum is important in the inhibiting effect, α-Al O is inert in ASR, the inhibiting effect increase as 2 3 the Al(OH)3 content increasing, the higher the alkali reactivity of the aggregate are, the higher the inhibiting effect is to get, the lower the alkali content are, the higher the inhibiting effect is to get. Al(OH)3 can inhibiting ASR may relate with the reeducation of the Ca(OH)2 content in hydration product. After c