压力对煤热解和煤气化的影响.pdfVIP

Energy Fuels 2007, 21, 3165–3170 3165 Influence of Pressure on Coal Pyrolysis and Char Gasification Haiping Yang,*,† Hanping Chen,† Fudong Ju,† Rong Yan,‡ and Shihong Zhang† State Key Laboratory of Coal Combustion, Huazhong UniVersity of Science and Technology, Wuhan 430074, P. R. China, and Institute of En Vironmental Science and Engineering, Nanyang Technological UniVersity, InnoVation Center, Block 2, Unit 237, 18 Nanyang DriVe, Singapore 637723 Recei Ved May 20, 2007. ReVised Manuscript ReceiVed August 6, 2007 Coal char structure varied greatly with pyrolysis pressure, which has a significant influence on the gasification reactivity. In this study, the influence of pressure on the behavior of coal pyrolysis and physicochemical structure and gasification characteristics of the resultant coal char was investigated using a pressurized thermogravimetric analyzer combined with an ambient thermogravimetric analyzer. First, the pyrolysis of Shenfu (SF) bituminous coal was performed in a pressurized thermogravimetric analyzer (TGA) at different pressures (0.1, 0.8, 1.5, 3, and 5 MPa). The volatile mainly evolved out at 400–800 °C. The gas products are mainly CO , CO, CH , and 2 4 light aliphatics with some water. It was observed that the pyrolysis of coal was shifted to lower temperature (50 °C) with pressure increasing from ambient to 5 MPa, and the devolatilization rate of coal pyrolysis was decreased and the coal char yield was increased slight