碳纳米管促进的Co_Mo_K硫化物基催化剂用于合成气制低碳混合醇.pdfVIP

27 11 　　　 2006 11 Vol.27 No.11 ChineseJournal of Catalysis November 2006 :0253-9837(2006)11-1019-09 :1019 ～1027 Co-Mo-K 马晓明, 　林国栋, 　张鸿斌 (厦门大学化学化工学院, 固体表面物理化学国家重点实验室, 福建厦门361005) :(CNT), CNT Co- o-K ., CNT , CNT CO . 5.0 Pa, 623 K, V (CO)∶V(H )∶V(N )=45∶45∶10, GHSV=3600 ml/(g·h), Co o K -10%CNT CO 2 2 1 1 0.3 21.6%, (C )241.5 mg/(g·h), C /C =1.39 (C ). CNT 1～4 2+ 1 Co o K CO, o 1 1 0.3 4+ ( o );, CNT H , 2 .. :;;;;;;;; :O643　　　:A Co-Mo-K Sulfide-Based Catalyst Promoted by Multi-walled Carbon Nanotubes for Higher Alcohol Synthesis from Syngas ＊ MA Xiaoming, L IN Guodong, ZHANG Hongbin (College of Chemistry and Chemical Engineering, State Key Laboratory of Physical Chemistry of Solid Surf aces, X iamen University, X iamen 361 5, Fuj ian, China) Abstract:Using home-made multi-walled carbon nanotubes (CNT)as the promoter, sulfurized Co- o-K cata- lysts (denoted as Co o K -x %CNT )were prepared by the co-precipitation method.Their catalytic perfor- i j k mance for higher alcohol synthesisfrom syngaswas evaluated and comparedwith that of the CNT-free counter- part (Coi oj Kk ).Appropriate incorporation of a minor amount of CNT into Coi oj Kk led to a significant in- crease in CO conversion and selectivity for the higher alcohols.Under the reaction conditions of 5.0 P