含有部分氧化磷的加强的粘土板房星族聚醚酰胺的纳米复合性材料.pdfVIP

Polym. Bull. (2012) 68:375–390 DOI 10.1007/s00289-011-0544-6 ORI GIN AL PA PER Clay-reinforced semi-aromatic polyether-amide nanocomposites containing phosphine oxide moieties: synthesis and characterization Meisam Shabanian • Khalil Faghihi • Fatemeh Shabani Received: 28 November 2010 / Revised: 3 June 2011 / Accepted: 3 June 2011 / Published online: 12 June 2011 Springer-Verlag 2011 Abstract Semi-aromatic flame retardant polyether-amide/organoclay nanocom- posites were synthesis through solution blending technique. Surface modification of the montmorillonite clay was performed with 1,4-bis[4,40 -amino phenoxy]butane for ample compatibilization with the polyamide matrix. The polymer chains were produced from the poly condensation reaction of bis(3-amino phenyl)phenyl phosphine oxide (4) with 1,4-(4-carboxy phenoxy)butane (3). The effect of clay dispersion and the interaction between clay and polyamide chains on the properties of nanocomposites were investigated using X-ray diffraction, scanning electron microscopy, limited oxygen index, differential scanning calorimetry, thermogravi- metric analysis, and water uptake measurements. The diacid 3 as a monomer was prepared from the reaction of 4-hydroxy benzoic acid (1) with 1,4-dibromo butane (2) in the presence of NaOH solution. Keywords Nanocomposites Flame-retardant polymers Organoclay Polyamide Introduction Polymer–clay nanocomposites have received significant attention, since the first report of polyamide-6-clay nanocomposites by Toyota’s research group in 1990 [ 1]. Subsequent studies have discovered that physical and chemical properties of organic polymers, such as thermal stability, [2] mechanical strength, [3] solvent resistance, [4] flame retardation, [5] ionic conductivity, [6] corrosion resistance, [7] gas barrier properties, [8], and dielectric properties [9] are substantially i