热重法研究的论文煤焦-CO2催化气化特性.pdfVIP

热重法研究煤焦-CO 催化气化特性 2 陈亚妮 闫鹏 郭晓滨 徐龙 马晓迅* 西北大学化工学院，陕西 西安 710069 摘要：利用热天平采用程序升温法对黄土庙、锦界两种煤焦进行了 CO2 催化气化反应性实 验，实验选取碱金属的几种催化剂，考察了不同催化剂对煤焦气化的催化效果。通过对实验 数据的处理，比较了煤焦催化气化的失重率、最大失重温度和最大气化反应速率三项指标， 分析后得出 Li CO 、Na CO 、KCl 的催化效果较为明显，同时得出不同阴阳离子的催化作 2 3 2 3 - 2- 2- - 2- + + + 用大小顺序为：Cl CO SO CH COO NO ；Li Na K 。 3 4 3 3 关键词：催化气化；催化剂；热重 Study on CO Catalytic Gasification of Coal Chars by TGA 2 CHEN Yani YAN Peng GUO Xiaobin XU Long MA Xiaoxun Department of Chemical engineering, Northwest University, Xi’an 710069, Shaanxi China Abstract: The CO2 catalytic gasification reactivity test of two caol chars from Huangtumiao and Jinjie, were conducted in laborary with TGA by temperature-programmed thermogravimetry. Several catalysts from Alkali metals were selected in this research, and catalytic effects of coal char gasification for different catalysts were reviewed. From the data treatment, which taken from test, three indexes of weight loss rate, the greatest weight loss temperature and the largest gasification rate were compared and analyzed, it was concluded that: catalytic effects of Li CO , 2 3 Na CO , KCl were obvious, simultaneously, catalysis of different Yin and Yang ions are in order: 2 3 - 2- 2- - 2- + + + Cl CO SO CH COO NO ；Li Na K . 3 4 3 3 Key words: catalytic gasification; catalyst; TGA 联系人：马晓迅。电话：029。E-mail ：maxym@ 第一作者：陈亚妮（1984－），女，硕士研究生，E-mail ：chenyani0320