三羧基丁烷膦酸锆%2fSPPEK复合膜在高温不同湿度下电导率研究.pdfVIP

三羧基丁烷膦酸锆/SPPEK复合膜在高温不同湿度下电 导率的研究 黄绵延，陈华艳，许莉，王宇新 （天津大学化工学院，化学工程联合国家重点实验室，化学工程研究所，天津, 300072 ） 摘 要 磺化杂萘联苯聚醚酮 （SPPEK）膜在温度高于 100℃时会因严重失水而电导率急剧下降。为此，本研究 中我们合成出具有较高电导率的吸湿性质子导体1,2,4-三羧基丁烷-2-膦酸锆(Zr(PBTC)) ，并将其掺杂到SPPEK （DS=67.2% ）中制备出Zr(PBTC)/SPPEK复合膜。实验表明，Zr(PBTC)的掺杂能有效提高复合膜在高温低湿 情况下的吸水能力，从而提高其电导率。SPPEK膜在 120℃时相对湿度为 40 ％情况下电导率仅有大约 10-4 S.cm-1，而相同条件下30wt.% Zr(PBTC)/SPPEK复合膜的电导率是它的20倍，达到2×10-3 S.cm-1 。而且相对湿 度越小，复合膜电导率的提高幅度越大，在相对湿度小于 20%时，复合膜的电导率大约比SPPEK膜髙两个数 量级。 关键词：磺化杂萘联苯聚醚酮，复合膜，相对湿度，电导率 A Study on the Conductivity of Zr(PBTC)/SPPEK Composite Membrane under High Temperature and Different Humidity HUANG Mian-yan, CHEN Hua-yan, XU Li, WANG Yu-xin (State Key Laboratory of Chemical Engineering, Chemical Engineering Research Center, School of Chemical Engineering and Technology , Tianjin University , Tianjin ，300072, China ) Abstract Sulfonated poly(pathalazinone ether ketone) (SPPEK) is an alternative 收稿日期：2006-7-31 作者简介：:黄绵延，1977 年生，博士研究生，E-mail:huangmianyan@, TEL:022 基金项目：国家自然科学基金 ）和天津市科技发展计划项目（05YFJZJC00600 ） membrane material for direct methanol fuel cells for its reasonable conductivity and methanol resistance. However, its conductivity depends much on the water content. At the temperature higher than 100 ℃, the conductivity of SPPEK membrane drops sharply due to the evaporation of water. The present paper focuses on improving the water holding ability of SPPEK membrane under intermediate temperature and low humidity by embedding the hygroscopic proton conductor. In present research, zirconium tricarboxybutyl phosphonate (Zr(PBTC)) was chosen as hygroscopic additives for its relative high conductivity. Zr(PBTC)/SPPEK composite membrane was obtained by casting homogeneous mixture of Zr(PBTC) and SPPEK （DS=6