聚乙二醇_功能化石墨烯层状纳米复合材料热稳定性的提高_张树鹏著.pdfVIP

2012 年第70 卷 化 学 学 报 Vol. 70, 2012 第12 期, 1394～1400 ACTA CHIMICA SINICA No. 12, 1394～1400 ·研究论文· 聚乙二醇/功能化石墨烯层状纳米复合材料热稳定性的提高 张树鹏* (南京理工大学 软化学与功能材料教育部重点实验室 南京 210094) 摘要 通过溶液共混技术成功制备了一系列聚乙二醇功能化石墨烯(GO-PEG)填充的聚乙二醇 4000(PEG4000)基纳米 复合材料. 利用红外(FT-IR)、X 衍射(XRD)、扫描电镜(SEM)、热重(TG)及玻璃化转变温度(Tg)等表征手段详细研究了 复合材料的结构和热性能. 结果表明: GO-PEG 可均匀分散在聚合物基体中, 纳米复合材料呈层状结构; 组分间的较强 界面相互作用协同增强了纳米复合材料的热稳定性能. 最终提出了层状纳米复合材料的形成过程及机理. 关键词 功能化石墨烯; 聚乙二醇; 复合材料; 热稳定性; 层状结构 Layer-aligned Polyethylene Glycol/Functionalized Graphene Composites with Improved Thermal Stability Zhang, Shupeng* (Key Laboratory for Soft Chemistry and Functional Materials of Ministry of Education, Nanjing University of Science and Technology, Nanjing 210094) Abstract PEG4000-based polymer nanocomposites filled with a series of PEG functionalized graphene (GO-PEG) have been prepared by solvent blending. The structure and properties of these nanocomposites could be studied by Fourier transform infrared spectroscopy (FT-IR), X-ray powder diffraction (XRD), scanning electron microscopy (SEM) and thermogravimetric analysis (TG) in detail. The results indicate that functionalized graphene is dispersed on a molecular scale and the corresponding composites show the layer-aligned structures. The thermal stability of polymer nanocomposites could be improved significantly by the strong interfacial interactions between both components mainly. At last, the schematic illustration of the