生物油组分分析与生物油%2f柴油的乳化研究.pdfVIP

生物油组分分析及生物油/柴油的乳化研究* 1 1 1** 1 2 沈丰菊 王丽红 易维明 柏雪源 吴 娟 (1 山东理工大学轻工与农业工程学院 山东淄博 255091) (2 山东工业职业学院 山东淄博 256414) 摘 要 采用流化床热解玉米秸秆，反应温度为 500℃，得到生物油。利用气相色谱/质谱分析（GC/MS ）对生物油进行成 分分析，主要成分除水之外，还含有羟基丙酮、乙酸、呋喃、苯酚及其衍生物等。选用亲油性 Span-80 和亲水性 Tween-20 两种乳化剂，按照一定比例混合后作为乳化剂。将生物油、柴油和乳化剂按照不同配比制成乳化油，通过实验，得出乳化 油稳定性与三者之间比例和均质时间的关系。并测定了乳化油物性参数与生物油浓度的关系。 关键词 热解；生物油；气相色谱/质谱分析；乳化 Compositional Analysis of Bio-oil and Emulsification of bio-oil in diesel fuel 1 1 1 1 2 SHEN Fengju ,WANG Lihong ,YI Weiming **,BAI Xueyuan ,WU Juan 1 ( School of Light Industry and Agriculture Engineering, Shandong University of Technology, Zibo 255091, Shandong,China) 2 ( Shandong Vocational College of Industry, Zibo 255091, Shandong,China) Abstract The bio-oil derived corn straw in a fluid bed reactor when the temperate of reaction is at 500 ℃. The bio-oil comprises of two fractions －water-soluble and water-insoluble fraction. After analyzed by gas chromatography/mass spectrometry (GC/MS), except for water, the major components of water-soluble fraction are acetic acid, 1-Hydroxy2-butanone, Furans, Phenol and its derivates. The surfactant was a kind of mixture made by Span-80 and Tween-20 according to a certain proportion. The emulsions products made by bio-oil, diesel fuel and emulsifier mixed together, and the conclusion is that the stabilization of emulsions products is relate to the reaction time, concentration of bio-oil and diesel fuel. The relation between physica