有机光电半导体材料及其未来之应用.pptVIP

T.-F. Guo NCKU Institite of Electro-Optical Science Engineering 有機光電半導體材料及其未來之應用 Institute of Electro-Optical Science and Engineering, National Cheng Kung University, Tainan, Taiwan 701 成功大學 光電科學與工程研究所 01/16/2007 Outlines Semiconductors Organic semiconductors (energy and delocalization of charge carriers) OLEDs and PLEDs 基礎原理和應用 Organnic photovoltaic and solar cells Conclusions Energy Band Diagram of a conductor, semiconductor, and insulator Bang Gap of Polyacetylene Conclusions Organic electronics乃是一項跨領域的學科，涵蓋半導體元件物理、基礎物理、電機、化學、材料…而基礎物理化學的基礎更是為重要。 Flexible devices (軟性電子) 將是未來科技的一項研究重點，此乃organic electronics之發展強項。 20 inches, amorphous Si, active matrix, full color OLED display WXGA (1280 x 768 pixels), 25 W, 300 cd/m2, CMO 03/12/2003 Recent progress of EL Panels Kodak digital camera, available on April 2003 Ink-jet printed EL display, Toshiba and Epson 2002 Reasons for organic solar cells Organic solar cells: moderate efficiencies and very low cost Inorganic photovoltaic cell S.E. Shaheen, D.S. Ginley, G.E. Jabbour, Mrs. Bull., 30, pp.10-18(2005). A Flexible, printed plastic solar cell with high efficiency made by SIMENS AG hν Flexible Donor-acceptor type solar cells Working principle of organic solar cell A Donor - Acceptor type bulk heterojunction solar cell Metal electrode (Al, Ca/Al etc.) hν e- h+ EF HOMO PCBM LUMO Acceptor LUMO Donor HOMO Donor ITO/PEDOT e- h+ h+ h+ e- Donor + Acceptor Metal electrode ITO hν Donor-P3HT Acceptor-PCBM T.-F. Guo NCKU Institite of Electro-Optical Science Engineering J (photo-current density) – V (Bias) curves for devices with Al and Ca/Al as the cathodes 2.142% 0.423 -3.691 0.426 -8.153 0.564 Al 4.383% 0.566 -10.433 0.382 -12.933 0.544 Ca/Al ηpower Fill Factor Jmpp(mA/cm2) Vmpp(V) Jsc(mA/cm2) Voc(V) Cathode material Incident power of 90mW/cm2 Future of Information Display * 郭 宗 枋 助理教授 Fundamental science of inorganic semiconductors Typical Semiconducting Materials (a) a conductor (b) a semiconductor (c) an insulator