第四章 分析化学中的化学平衡.pptVIP

* * * * * * * * * 缓冲溶液的选择原则 不干扰测定 例如：EDTA滴定Pb2+,不用HAc-Ac- 有较大的缓冲能力，足够的缓冲容量 较大浓度 (0.01～1mol·L-1); pH≈pKa 即ca∶cb≈1∶1 HAc— NaAc : pKa=4.76 (4~5.5) NH4OH—NH3: pKb=4.75 (8~10 ) (CH2)6N4— (CH2)6N4H+: pKb=8.87 （4.5~6） Preparation of buffers A buffer solution of any desired pH can be prepared by combing calculated quantities of a suitable conjugate acid/base pair. Prepared buffers by making up a solution of approximately the desired pH and then adjust by adding acid or conjugate base until the required pH is indicated by a pH meter. * * * * * * * *