热浸镀锌钢板钼酸盐复合钝化膜的耐腐蚀性能.pdfVIP

37 1 Vol. 37 No. 1 2011 2 Journal of Lanzhou University of Technology Feb. 2011 :2011) 热浸镀锌钢板钼酸盐复合钝化膜的耐腐蚀性能 何世权, 钟 辉, 刘 飞, 田 禾, 苏 燕 ( , 730050) : 应用极化曲线和电化学阻抗谱方法研究钼酸盐与 烯酸树脂复合钝化膜在 3. 5% 的NaCl 溶液中的电化学 性能, 采用中性盐雾试验和盐水浸泡试验检测试样耐腐蚀性能, 利用扫描电子显微镜观察钝化膜的微观形貌. 与未 经钝化的热浸镀锌钢板和经铬酸盐钝化的热浸镀锌钢板相比, 钼酸盐与 烯酸树脂复合钝化的热浸镀锌钢板抗腐 蚀性较好, 其腐蚀电位更正, 腐蚀电流更小, 在 3. 5% 的NaCl 溶液中的阻抗更大, 中性盐雾试验和盐水浸泡试验中 表现出的抗腐蚀性能更好, 钝化膜更致密平整. : 热浸镀锌; 无铬钝化; 钼酸盐; 烯酸; 耐腐蚀 : TG 174 : A Anticorrosion performance of molybdate composite passivation film on hotdip galvanized steel HE Shiquan, H ONG Hui, LIU Fei, TIAN H e, SU Yan ( College of Petrochem ical T echnology, Lanzhou Univ. of T ech. , Lanzhou 730050, China) Abstract: Electrochemical behavior of the molybdate and acrylic composite passivation film in 3. 5% NaCl solution was studied by using polarization curve and electrochemical impedance spectrum( EIS) techniques. Anticorrosion performance of the tested sample was tested with salt spraying and salt water immersion method. Scanning electron microscopy( SEM) was used to observe the micromorphology of the film. Com pared with unpassivated hotdip galvanized steel and chromate passivated hotdip galvanized steel, it was found that anticorrosion performance of the molybdate and acrylic composite passivated hotdip galvanized steel was better, in connection with higher corrosion potential, lower corrosion current, higher impedance in 3. 5%NaCl solution. Even better was the anticorrosion performance in salt spray test and salt water im mersion test, showing more compact and smoother passivation film. Key words: hotdip galvanization; chromefree passivation; molybdate; acrylic acid; corrosion resistance , , , , . 3 000 h. , , , , , ,