环保型含氟共聚物石材防护剂的合成及性能研究.pdfVIP

39 Vol39 No4 20114 NEW CH EM ICAL MATERIALS 45 尹晓康 张庆华 詹晓力 陈丰秋 ( 浙江大学化学工程与生物工程学系, 杭州310027) 以自制的环保型 氟单体丙烯酸( N甲基全氟 丁烷磺酰胺基) 乙酯, 3甲基丙烯酰氧基丙 基三甲氧基硅烷( KH570) 和丙烯酸十八酯( SA) 为共聚单体, 采用溶液聚合的方式合成得到 氟三元 共聚物探讨了聚合参数对转化率的影响, 利用红外光谱仪( FTIR) 和表面张力仪表征了共聚物的结 构和表面性能, 并研究了所合成的共聚物对饰面石材表面的防护作用结果表明: C4SA/ KH570/ SA 共聚物具有较低的表面能, 且表面能随氟代丙烯酸酯的 量增加而逐渐降低, 并最终趋于稳定; 经其处 理后的饰面石材具有良好的耐污特性, KH570 的引入加强了共聚物涂层与基材的粘结强度, 提高了耐 水及耐酸碱的特性 环境友好, 氟共聚物, 疏水疏油, 石材防护 Synthesis and characterization of ecof riendly fluori nated acrylate copolymers as stone protecti ve agent Yin Xiaokang Zhang Q inghua Zhan Xiaoli Chen Fengqiu ( U NILAB Research Center of Chemical Reaction Engineering, Zhejiang U niversity , H angzhou 310027) Abstract A random copolymer w as prepared by free radical solution polymerizat ion using the self synthesized eco friendly [ Nmethylperfluorobut ane1sulfonam ide] ethyl acrylate ( C4SA) , stearyl acrylate( SA) and 3Methacryloxypro pyltrimethoxysilane( KH570) . The relationship betw een polymerization condition and conversion rate w as discussed to maximize the conversion. Structure and surface property w as characterized by Fourier t ransform inf rared ( FTIR) spec trum and opt ical contact angle meter, and then the stone prot ection effect of the copolymer w as tested. It shown that the copolymer had very low surface energy, which gradually decreased to a constant level w hile the fluorine content in creased. T he stone treated by the copolymer show ed exceptional stainresistant property , also the w ater and acid/ base re sistant property w ere greatly increased by int roducing KH 570.