炼厂气分析方法.docVIP

0908222106 相互作用 杜玥莹 应用化学 摘 要 炼厂气组成分析是炼油厂气体常规分析项目，对其分析的准确程度直接关系到原油加工过程工艺条件的控制，再者，炼厂气是非常重要和宝贵的石油化工产原料，分析其组成对其进一步加工应用有重要意义。 多维气相色谱法分析炼厂气是一种成熟的分析方法，五柱四阀双热导检测体系是石化行业主要分析模式。但在实际分析具体应用时，对其方法的建立与调试是由多方面因素影响与决定的。 本文重点从气相色谱的发展和原理、仪器配置及组成、色谱柱及柱温选择、气化室温度和检测器温度选择、实验操作及定性定量方法等方面讨论了色谱分析方法的建立过程与相关的注意事项。 实践证明多柱多阀组合技术的多维气相色谱分析法在炼厂气分析中有其独特的优势，但也有其无法避免的局限性。 关键词:气相色谱法;平面六通阀;热导检测器;炼厂组成;方法建立 Abstract The refinery gas composition analysis is the refinery gas routine analysis project, directly relates the crude oil processing process technological conditions to its analysis accurate degree the control, furthermore, the refinery gas is extremely important and precious petroleum chemical industry product raw material, analyzes its composition to have the vital significance to its progress processing application. The multi-dimensional gas phase chromatography analysis refinery gas is one mature analysis method, five column four valve double heat conductivity examination system petrifies the profession main analysis pattern. But when actual analysis concrete application, to its method establishment and the debugging is by the various factor influence and the decision. This article key from instrument aspects and so on disposition and correlation appendix, chromatographic column and column warm choice, carrier gas type and speed of flow choice, carburetor temperature and detector temperature choice, specimen handling way and qualitative quantitative method discussed the chromatograph analysis method establishment process and the correlation matters needing attention. The practice proved the multi-columns send the valve combination technology the multi-dimensional gas chromatography analytic method to have its unique superiority in the refinery gas analysis, but also has the limitation which it is unable to avoid. Key words: Gas phase chromatography; Six-way valve; Double hea