水中典型内分泌干扰物质的臭氧氧化研究.pdfVIP

28 Vol. 28, No. 200 ENVIRONMENTAL SCIENCE Jul. , 200 * , , , , , 150090 : , HCO- pH O EDs E1E2EE2DES 3 3 4nNP . , 5 EDs O , O 636 gL920 % EDs, 3 3 HCO- 0~ 100 mgL O , O EDs pH . pH 0 3 3 3 6 - 1 pH 106 , O3 5 EDs 20 05 16 ~ 389 10 L mols 093~ 9 - 1 1 5 10 L mols , 5 O3 . 5 EDs 20 9 9 - 1 5 05 , O EDs [ 12 1 10 ~ 381 10 L mols ] EDs [ 62 10 ~ 3 6 - 1 3 4 255 10 L mols ] 10 ~ 10 . O3 EDs , EDs 265% ~ 503% 5 3% ~ 20 % , , EDs O3 . : ; ; ; ; : X 03. 1 : A : 0250330 1 200 0 146606 Ozonation of Representative Endocrine Disruptors EDs in Water LIU Guifang, MA Jun, QIN Qingdong, LI Xuchun, LI Guibai School of Municipal and Environmental Engineering, Harbin Institute of Technology, Harbin 150090, China Abstract: The eff ects of ozone dose, bicarbonate concentration and pH on endocrine disruptors EDs removal , such as E 1E2EE2DES and 4nNP, were investigated through batch experiment . The results indicated that the removal rates were enhanced by increasing ozone dose, and O3 exposures of only 636 gL were calculated to achieve 920 % EDs removal efficiency. The presence of bicarbonate 0~ 100 mgL inhibited EDs ozonation. Furthermore, the EDs removal rates increased signif icantly as pH increased . The f ive apparent rate constants 20 6 - 1 05 of ozone w ith the f ive EDs w ere in the range of 16 ~ 389 10 L mols at neutral pH pH 0 and 093~ 1 5 9 - 1 10 L mols at basic pH pH 106 . It w as indicated that the five EDs w ere removed rapidly by O3 in w ater. At the same time, the 9 elementary reaction ozone rate constants 20 05 were calculated , and the reactivity of ozone w ith ionized EDs [ ie. 121 10 ~ 9 - 1 3 4 5 6 - 1 38 1 10 L mols ] w as 10 ~ 10 times higher than w ith neutral EDs [ i. e. 62 10 ~ 255 10 L mols ] . The comparative test of EDs ozonation under diff erent w ater quality conditions indicated tha