付科反应中使用的固体催化剂.pdfVIP

Chem. Rev. 2006, 106, 1077−1104 1077 Use of Solid Catalysts in Friedel−Crafts Acylation Reactions† Giovanni Sartori*,‡,§ and Raimondo Maggi‡,§ Clean Synthetic Methodologies Group and National Interuniversity Consortium “Chemistry for Environment” (INCA), Unit PR2, Dipartimento di Chimica Organica e Industriale dell’Universita`, Parco Area delle Scienze 17A, I-43100 Parma, Italy Received September 23, 2005 Contents substrate with an acyl component in the presence of a catalyst.3 1. Introduction 1077 Since the above communication, an impressive number 2. Acylation of Arenes 1078 of papers and books have been published and numerous 2.1. Acylation with Zeolites 1078 patents have been registered on this topic.3 The reaction 2.2. Acylation with Clays 1083 quickly became a fundamental pillar of synthetic organic 2.3. Acylation with Metal Oxides 1084 chemistry at both the academic and industrial levels. The 2.4. Acylation with Acid-Treated Metal Oxides 1084 great interest in electrophilic acylation studies and in the 2.5. Acyla