离子色谱法的研究季铵盐萃取硫酸的机理.pdfVIP

第9 届全国离子色谱学术报告会论文集(北京 2002) 制作 离子色谱法研究季铵盐萃取硫酸的机理 1∗ 2 2 1 1 唐红萍 杨海军 丁明玉 杨明德 何培炯 1 2 清华大学, 核能技术设计研究院 化学系 北京100084 摘要 季铵盐可以直接从氰化浸出液中萃取金 但反萃困难 酸性硫脲通空气体系能有效反 萃季铵盐有机相中的氰化金 但实验发现 在用硫酸硫脲溶液反萃时 硫酸会进入有机相被 萃取 导致水相硫酸减少 本文用抑制型离子色谱法测定季铵盐萃取硫酸过程中阴离子浓度 的变化 以研究硫酸的萃取机理 结果表明 尽管季铵盐的萃取机理一般为阴离子交换 但 在一定条件下硫酸主要以中性分子形式被萃取形成氢键缔合物 只有少量硫酸以硫酸氢根形 式通过阴离子交换被萃取 氢键缔合在季铵盐反萃过程中不可忽视 关键词 离子色谱 溶剂萃取 硫酸 季铵盐 Ion Chromatography Study on the Extraction Mechanism for Sulphuric Acid by Quaternary Ammonium Salt 1 2 2 1 1 Tang Hongping , Yang Haijun , Ding Mingyu , Yang Mingde , He Peijiong 1. Institute of nuclear energy and technology, Tsinghua University, Beijing, 100084; 2. Department of Chemistry, Tsinghua University, Beijing, 100084 Abstract: Quaternary ammonium salt (N263) has strong affinity with gold in cyanide solutions, but it is not readily stripped. Stripping with acidic thiourea solutions and air sparging shows promise, but it is found that sulphuric acid is extracted into organic phase during stripping process. In this - 2- paper, Cl and SO4 exchange amount during N263 extracting sulphuric acid is determined by suppressed ion chromatography with NaHCO /Na CO as eluent t. It is shown that sulphuric acid 3 2 3 is extracted mainly as neutral molecule H2SO4 held with N263 by hydrogen bond and a few as HSO4-, although N263 ’s extraction mechanism is commonly anion exchange. Extraction by hydrogen bond can’t be ignored when sulphruic acidic thiourea solution stripping from N263 loading gold-cy