氨基化二氧化硅包覆碳纳米管增 强环氧树脂复合材料.docVIP

文章编号：1673-2812 (201) 04-0001-06 氨基化二氧化硅包覆碳纳米管增强环氧树脂复合材料 郭唐华，陈圣岳，彭 懋 （高分子合成与功能构造教育部重点实验室，浙江大学高分子科学与工程学系，浙江 杭州 310027） 【摘 要】MWNTs-OH），然后将MWNTs-OH分散于乙醇溶液中，加入正硅酸乙酯（TEOS），通过St?ber法制备了表面包覆二氧化硅的碳纳米管（MWNTs-SiO2）；将MWNTs-SiO2进一步与氨丙基三乙氧基硅烷反应，得到氨基化二氧化硅包覆碳纳米管（MWNTs-SiO2-NH2）。将所制备的MWNTs-SiO2-NH2与缩水甘油醚型环氧树脂E-44复合，并以三乙醇胺为固化剂，得到氨基化碳纳米管/环氧树脂复合材料。实验结果表明，碳纳米管表面成功地引入了氨基基团；表面氨基化碳纳米管在环氧树脂基体中的分散性得到了显著的提高，同时氨基化碳纳米管能够显著地提高复合材料的冲击强度和拉伸强度。 【关键词】 中图分类号：T 文献标识码：A Reinforcement of Epoxy Resin with Aminated Silica-Encapsulated Carbon Nanotubes G Tang-hua，CHEN Sheng-yue，PENG Mao (MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China) 【Abstract】 A novel method was utilized to modify the surface of multi-walled carbon nanotubes (MWNTs) for the preparation of nanocomposites with epoxy resin as the matrix, triethanolamine as the curing agent and the modified MWNTs as the reinforcing fillers. MWNTs were first treated with ethanol solution of KOH to introduce hydroxyl groups to the nanotube surfaces. The hydroxylized MWNTs were further encapsulated with silica by St?ber method, and then treated with a silane coupling agent to introduce amino groups to the nanotube surfaces. Fourier transform infrared spectroscopy and scanning electron microscopy show that the surface of MWNTs was successfully encapsulated with SiO2 nanoparticles and decorated with amino groups. Optical microscopy showed that the modified MWNTs exhibit good dispersibility in epoxy resin when the content of nanorubes is below 1 wt%. Study of mechanical properties showed that the modified nanotubes obviously increased the tensile strength, impact strength and modulus of epoxy resin. This method is simple but efficient for the surface modification of MWNTs and the preparation of high performance epoxy nanocomposites. 【Key words】ulti-walled carbon nanotubes；epoxy resin；amination；dispersity；mechanical properties 1 引 言 自1991年Ijima报