对于纯苯的研究.doc

华东理工大学 毕业论文 课 题 精对苯二甲酸装置－氧化反应单元 扩容改造 学 院 教育中心 南化教育中心 专 业 年 级 学 号 5738274 姓 名 陈雪阳 导 师 陈学梅 定稿日期： 2007 年 4 月 20 日 摘 要 摘要：扬子石化公司PTA装置于1978年底从德国鲁奇工程公司成套引进，采用美国阿莫柯（Amoco）专利技术，设计规模45万吨/年，由2条生产线组成，每条生产线规模为22.5万吨/年，年生产时间7600小时 。由于近年来聚酯工业的迅速发展，作为聚酯生产主要原料的PTA市场紧缺，扬子石化公司结合生产实践中的经验和对局部工序或设备提高负荷至扩能规模的经验，在现有的PTA装置基础上挖潜改造，氧化反应单元是其中的主要部分对氧化反应单元工艺参数进行最优化设计、、、PX初浓度、停留时间等因素的影响冷凝系统的设计解决扩容改造的瓶颈问题PTA plant of Yangzi Petrochemical Company Ltd.(YPC), introduced from German Lurgi Engineering Company at the end of year 1978, using American Amoco License, is comprised of two production lines with design capacity of 450,000 t/y (225,000t/y of each line, annual production time of 7600 hours). Due to rapid development of polyester industry, PTA, as the main raw material of polyester production, is in short supply. YPC has made modifications based on its practical production experience and experience in increasing equipment load as well as experience in revamping to tap the potential of the plant, especially for oxidation unit. In this paper, optimum design to process parameters of oxidation unit is given. Process operating conditions are gained by analysis of effects on reaction of different factors, such as air input, agitating speed, preparation radio of cat and its amount, initial concentration of PX, initial water content, temperature, and residence time. Design for condensing system is completed by material balance and basis design of the first condenser and the second condenser. Through the design, partial bottle problems are solved and plant capacity is increased from 450,000t/y to 600,000t/y. Keywords: PTA，Oxide Reaction，Design 1 1.1扬子石化公司60万吨/年PTA改造 ……………………………………………………1 精对苯二甲酸的性质和用途………………………………