用Mo络合催化剂将CO_2转化为有机化合物效率高成本低.pdfVIP

第 7期 梁吉雷，等．劣质柴油加氢改质催化剂的制备及其应用 I．催化剂制备方法及其催化四氢萘的反应规律 41 PREPARATION AND APPLICATIoN oF HYDRoUPGRADING CATALYST FOR INFERIOR DIESEL PartI．CATALYST PREPARATION M ETHoD AND SELECTIVE RING—oPENING oF TETRALIN LiangJilei，LiuYunqi，WangLiqiang，LiuChenguang (StateKeyLaboratoryofHeavyOilProcessing，KeyLaboratoryofCatalysisof ChinaNationalPetroleumCorporation (CNPC)，UniversityofPetroleum (EastChina)， Qingdao，Shandong266555) Abstract：Tetralinhydroconversionprocessisacomplexreactionconsistingofthehydrogenation， dehydrogenation， isomerization， ring—opening， alkyl and transaIkyIation． Unsupported Ni—M o—W hydroupgradingcatalystswerepreparedbythreedifferentpreparationmethods(drymixing，wetmix— ing，CO—gelling)，andtetralinwasselectedasamodelcompoundtoevaluatethehydrogenationandselec— tivering—openingperformanceofthecatalysts．Theresultsshow thatthecatalystpreparedbyCO—gelling showshigherhydrogenationconversionoftetralinaswellashigherselectiveringopeningandisomeriza— tionperformancethantheothertwocatalysts．Thewetmixing catalysthasahighhydrogenationselec— tivityandtetralinconversionrate，butlowerinisomerizationandring—openingselectivity．Thetetralin conversionrate，theisomerization selectivityandthehydrogenationselectivityarelow forthedrymix— ingcatalyst．Thesinglemoleculemechanism ismainlyfollowedfortetralinhydrogenationandring一0一 peningreactionsovertheCO—gellingandwetmixing catalyst。inducing 1essheavyproductsand coke． TheunsupportedNi—M o—W hydroupgradingcatalystpreparedbyCO—gellingshowsthedesireddearomati— zationperformancebyselectiveringopening． KeyW ords：tetralin；selectivering—opening；unsupportedcatalyst；hydroupgrading；inferiordiesel ：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：： — — ，0000e— 珥) 人研究过它与 C