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摘要
复合高吸水性树脂(SuperabsorbentComposite)是一种新型功能高分子材料。它具有吸收比自身重几百到几千倍水的高吸水功能,并且保水性能优良,一旦吸水膨胀成为水凝胶时,即使加压也很难把水分离出来。因此,它在个人卫生用品、工农业生产、土木建筑等各个领域都有广泛用途。
本文研究了CTS-g-P(AA-co-AM)/KL复合高吸水性树脂对甲基紫的吸附特性,考察了吸附时间,甲基紫的初浓度,pH,离子强度对吸附量的影响。结果表明随着吸附时间的延长,树脂对甲基紫的吸附量增加,24后,吸附作用基本达到平衡;吸附量随甲基紫初浓度的增大而增大;吸附量随pH增大先增加,当pH=4时达最大,此后,pH增大,吸附量下降;随着离子浓度的增加,吸附量呈下降趋势。CTS-g-P(AA-co-AM)/KL高吸水性树脂对甲基紫有很好的吸附作用,室温最大吸附量为1500mg/g,在印染废水处理过程中具有一定的应用价值。
关键词 复合高吸水性树脂;甲基紫;吸附
Abstract
Super?Absorbent?Polymer,SAP is a new type of functional polymer materials. It has sucked received more than a few hundred to a thousand times its own weight of water, high water absorption features, and excellent water retention, once the swelling became hydrogel, even pressure is difficult to separate the water. Therefore, it has a wide range of applications in various fields of personal hygiene products, industrial and agricultural production, civil construction, etc. Since so since the successful development of super absorbent polymers has been the worlds attention, the development of extremely rapid, the demand worldwide annually, has gradually expanded its field of application.
Setting methyl violet as an example,the adsorption characteristics of the Poly(Acrylic Acid-co-Acrylamide) superabsorbent resin to methyl violet and the influences of adsorption time, original density of methyl violet, pH, and ionic strength on the adsorption were investigated.the results show that along with the extending of adsorption time, the adsorption capacity of modified humic acid to methyl violet was increased,and after 24h,the adsorption got to the balance basically;Along with the extending of original density of methyl violet,the adsorption amount was increased;Along with the extending of pH ,the adsorption amount was increased.When pH=4,the adsorption amount got to the maximum .Afterwards, along with the extending of pH, the adsorption amount was descended;Along with the increment of ionic strength,the adsorption amount showed decreasing trend.
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